Photophysics of cavity-coupled quantum emitters in hexagonal boron nitride
Phys. Rev. B 113, 035424 – Published 15 January, 2026
DOI: https://doi.org/10.1103/x9xl-nmh9
Abstract
Room-temperature spin-optical active quantum emitters in hexagonal boron nitride (hBN) are promising candidates for advancing quantum photonic technologies; however, their inherently low photoluminescence (PL) quantum yield presents a significant challenge for optical readout. Here, we report a single-step coformation strategy that simultaneously creates plasmonic microcavities and quantum emitters in hBN via thermal annealing of substrates. This process produces an ultraclean, spacer-free cavity-emitter system with large-area integration capability. The resulting cavity-coupled emitters exhibit a increase in the overall PL intensity and a Purcell factor of , attributed to strong cavity-emitter coupling. The cavity-coupled system exhibited a reduced radiative lifetime of (radiative rate of ) compared to a cavity-free emitter of (radiative rate of ). Single-photon emission purity of was confirmed for emitters at 1.97 eV, while systematic analysis of emission dynamics revealed multilevel quantum system behaviors, which can be explained by using a scattering-Lindbladian-Hamiltonian (SLH) framework. These results demonstrate the control over emission properties through cavity design and emitter-cavity coupling, establishing a robust route toward integrated, room-temperature quantum photonic circuitry.