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    Photophysics of cavity-coupled quantum emitters in hexagonal boron nitride

    Sancia M. Tauro1, Jennifer Brumley1, Antonio Cobarrubia1,2, C. Abinash Bhuyan1, Diego V. Lundquist1, Eli Janzen3, Boris Kiefer4, James H. Edgar3, and Sanjay K. Behura1,*

    • *Contact author: sbehura@sdsu.edu

    Phys. Rev. B 113, 035424 – Published 15 January, 2026

    DOI: https://doi.org/10.1103/x9xl-nmh9

    Abstract

    Room-temperature spin-optical active quantum emitters in hexagonal boron nitride (hBN) are promising candidates for advancing quantum photonic technologies; however, their inherently low photoluminescence (PL) quantum yield presents a significant challenge for optical readout. Here, we report a single-step coformation strategy that simultaneously creates plasmonic microcavities and quantum emitters in hBN via thermal annealing of hBN/Au/SiO2/Si substrates. This process produces an ultraclean, spacer-free cavity-emitter system with large-area integration capability. The resulting cavity-coupled emitters exhibit a 247% increase in the overall PL intensity and a Purcell factor of 4.27±0.27, attributed to strong cavity-emitter coupling. The cavity-coupled system exhibited a reduced radiative lifetime of 0.33±0.01ns (radiative rate of ∼3.03GHz) compared to a cavity-free emitter of 1.41±0.08ns (radiative rate of ∼0.70GHz). Single-photon emission purity of 56% was confirmed for emitters at 1.97 eV, while systematic analysis of emission dynamics revealed multilevel quantum system behaviors, which can be explained by using a scattering-Lindbladian-Hamiltonian (SLH) framework. These results demonstrate the control over emission properties through cavity design and emitter-cavity coupling, establishing a robust route toward integrated, room-temperature quantum photonic circuitry.

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