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    V 3d and Se 4p spectral reconstruction by charge density wave formation in VSe2 probed by angle-resolved photoemission spectroscopy

    K. Fujinuma1,*, T. Hara2,†, M. Emi2, N. Katayama2,3, H. Sawa2,4, X. Zhao1, K. Takubo1, G. Tomassucci5, F. Minati5 et al.

    A. Barinov6, K. Ozawa7, N. L. Saini5, and T. Mizokawa1

    • *Contact author: kouto200081@fuji.waseda.jp
    • †Present address: Department of Physics, Tohoku University, Sendai 980-8579, Japan.

    Phys. Rev. B 113, 235112 – Published 5 June, 2026

    DOI: https://doi.org/10.1103/wrhd-mksr

    Abstract

    The electronic structure of VSe2 with 4×4×3.18 charge density wave (CDW) transition has been studied by means of angle-resolved photoemission spectroscopy (ARPES) and scanning photoemission microscopy (SPEM). The partial depletion of the Fermi surfaces is observed in the CDW phase by ARPES, consistent with that reported previously. A flat band with V 3d3z2−r2 character, which is observed near the Fermi level around the Γ point in the Brillouin zone, gains its spectral weight in the CDW phase while the holelike band around the A point loses its weight. The spectral weight redistribution across the CDW transition indicates an important role of the V 3d-Se 4p hybridization, associated with the out-of-plane displacement of Se reported by Petkov et al. [Phys. Rev. B 111, 014105 (2025)]. The electronic inhomogeneity observed by SPEM suggests different surface terminations of the CDW state with the strong lattice and electronic modulation along the out-of-plane direction.

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