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    Flat band driven itinerant magnetism in the Co-pnictides CaCo2As2 and LaCo2P2

    D. Subires1,2,*, M. García-Díez1,3, A. Kar1, C.-Y. Lim1, Victoria M. Li4, V Yannello5, Dina Carbone6, P. Gargiani7, T. Yilmaz8,9 et al.

    J. Dai7, M. Tallarida7, E. Vescovo8, M. Shatruk4, Maia G. Vergniory1,10, and S. Blanco-Canosa1,11,†

    • *Contact author: david.subires@dipc.org
    • †Contact author: sblanco@dipc.org

    Phys. Rev. B 112, 165141 – Published 27 October, 2025

    DOI: https://doi.org/10.1103/w9rw-rjdh

    Abstract

    Flat bands can induce strong electron correlation effects that help stabilize both magnetic and superconducting states. Here, we carry out angle-resolved photoemission spectroscopy and density functional theory calculations to study the electronic structure of the Co-pnictides CaCo2As2 and LaCo2P2. We find that the kz Fermi topology of ferromagnetic LaCo2P2 is markedly two-dimensional, while the antiferromagnetic CaCo2As2 develops a 3D Fermi surface described by a zigzaglike band dispersion perpendicular to the Co-As plane. Furthermore, the magnetism is driven by the electronic correlations of the flat bands with dxy and dz2 orbital character at the Fermi level. Our results link the electronic dimensionality and the magnetic order and emphasize the critical role of the As-As and P-P bond strength along the c direction to understand the electronic band structure and the rich phase diagram of transition metal pnictides.

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