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Spin liquids on the tetratrillium lattice

Matías G. Gonzalez1,2,3 and Johannes Reuther2,3

Phys. Rev. B 113, 054430 – Published 17 February, 2026

DOI: https://doi.org/10.1103/w2m6-bs9h

Abstract

The tetratrillium lattice has recently been proposed as being responsible for the dynamical properties observed in the S=1 langbeinite compound K2Ni2(SO4)3. Here, we study in detail the classical spin liquid properties of this lattice of tricoordinated tetrahedra using classical Monte Carlo and large-N theory calculations. In the large-N limit, we find that the system presents a gapped spectrum with flat bottom bands, giving rise to a fragile spin liquid with exponentially decaying correlations according to the classification of classical spin liquids. We confirm that this scenario also holds in the more realistic Ising and Heisenberg cases, for which the system does not exhibit any finite-temperature phase transition, and the low-temperature spin structure factors exhibit excellent quantitative agreement with the large-N theory. We also provide insight into the quantum S=1/2 limit by performing pseudo-Majorana functional renormalization-group calculations at finite temperatures, and we discuss the possible phases that can arise in the ground state due to quantum fluctuations.

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References (65)

  1. J. Villain, Insulating spin glasses, Z. Phys. B 33, 31 (1979).
  2. R. Moessner and J. T. Chalker, Properties of a classical spin liquid: The Heisenberg pyrochlore antiferromagnet, Phys. Rev. Lett. 80, 2929 (1998).
  3. L. Balents, Spin liquids in frustrated magnets, Nature (London) 464, 199 (2010).
  4. L. Savary and L. Balents, Quantum spin liquids: A review, Rep. Prog. Phys. 80, 016502 (2017).
  5. C. Broholm, R. J. Cava, S. A. Kivelson, D. G. Nocera, M. R. Norman, and T. Senthil, Quantum spin liquids, Science 367, eaay0668 (2020).
  6. N. Davier, F. A. Gómez Albarracín, H. D. Rosales, and P. Pujol, Combined approach to analyze and classify families of classical spin liquids, Phys. Rev. B 108, 054408 (2023).
  7. H. Yan, O. Benton, A. H. Nevidomskyy, and R. Moessner, Classification of classical spin liquids: Detailed formalism and suite of examples, Phys. Rev. B 109, 174421 (2024).
  8. H. Yan, O. Benton, R. Moessner, and A. H. Nevidomskyy, Classification of classical spin liquids: Typology and resulting landscape, Phys. Rev. B 110, L020402 (2024).
  9. S. T. Bramwell and M. J. Harris, The history of spin ice, J. Phys.: Condens. Matter 32, 374010 (2020).
  10. M. Hermele, M. P. A. Fisher, and L. Balents, Pyrochlore photons: The U(1) spin liquid in a S=12 three-dimensional frustrated magnet, Phys. Rev. B 69, 064404 (2004).
  11. M. J. P. Gingras and P. A. McClarty, Quantum spin ice: A search for gapless quantum spin liquids in pyrochlore magnets, Rep. Prog. Phys. 77, 056501 (2014).
  12. K. A. Ross, L. Savary, B. D. Gaulin, and L. Balents, Quantum excitations in quantum spin ice, Phys. Rev. X 1, 021002 (2011).
  13. O. Benton, O. Sikora, and N. Shannon, Seeing the light: Experimental signatures of emergent electromagnetism in a quantum spin ice, Phys. Rev. B 86, 075154 (2012).
  14. A. Szabó and C. Castelnovo, Seeing beyond the light: Vison and photon electrodynamics in quantum spin ice, Phys. Rev. B 100, 014417 (2019).
  15. M. J. Harris, S. T. Bramwell, D. F. McMorrow, T. Zeiske, and K. W. Godfrey, Geometrical frustration in the ferromagnetic pyrochlore Ho2Ti2O7, Phys. Rev. Lett. 79, 2554 (1997).
  16. A. P. Ramirez, A. Hayashi, R. J. Cava, R. Siddharthan, and B. S. Shastry, Zero-point entropy in ‘spin ice', Nature (London) 399, 333 (1999).
  17. S. T. Bramwell, M. J. Harris, B. C. den Hertog, M. J. P. Gingras, J. S. Gardner, D. F. McMorrow, A. R. Wildes, A. L. Cornelius, J. D. M. Champion, R. G. Melko, and T. Fennell, Spin correlations in Ho2Ti2O7: A dipolar spin ice system, Phys. Rev. Lett. 87, 047205 (2001).
  18. J. Lago, S. J. Blundell, and C. Baines, μSR investigation of spin dynamics in the spin-ice material Dy2Ti2O7, J. Phys.: Condens. Matter 19, 326210 (2007).
  19. B. Gao, T. Chen, D. W. Tam, C.-L. Huang, K. Sasmal, D. T. Adroja, F. Ye, H. Cao, G. Sala, M. B. Stone, C. Baines, J. A. T. Verezhak, H. Hu, J.-H. Chung, X. Xu, S.-W. Cheong, M. Nallaiyan, S. Spagna, M. B. Maple, A. H. Nevidomskyy, et al., Experimental signatures of a three-dimensional quantum spin liquid in effective spin-1/2 Ce2Zr2O7 pyrochlore, Nat. Phys. 15, 1052 (2019).
  20. R. Sibille, N. Gauthier, E. Lhotel, V. Porée, V. Pomjakushin, R. A. Ewings, T. G. Perring, J. Ollivier, A. Wildes, C. Ritter, T. C. Hansen, D. A. Keen, G. J. Nilsen, L. Keller, S. Petit, and T. Fennell, A quantum liquid of magnetic octupoles on the pyrochlore lattice, Nat. Phys. 16, 546 (2020).
  21. E. M. Smith, O. Benton, D. R. Yahne, B. Placke, R. Schäfer, J. Gaudet, J. Dudemaine, A. Fitterman, J. Beare, A. R. Wildes, S. Bhattacharya, T. DeLazzer, C. R. C. Buhariwalla, N. P. Butch, R. Movshovich, J. D. Garrett, C. A. Marjerrison, J. P. Clancy, E. Kermarrec, G. M. Luke, et al., Case for a U(1)π quantum spin liquid ground state in the dipole-octupole pyrochlore Ce2Zr2O7, Phys. Rev. X 12, 021015 (2022).
  22. A. Bhardwaj, S. Zhang, H. Yan, R. Moessner, A. H. Nevidomskyy, and H. J. Changlani, Sleuthing out exotic quantum spin liquidity in the pyrochlore magnet Ce2Zr2O7, npj Quantum Mater. 7, 51 (2022).
  23. D. R. Yahne, B. Placke, R. Schäfer, O. Benton, R. Moessner, M. Powell, J. W. Kolis, C. M. Pasco, A. F. May, M. D. Frontzek, E. M. Smith, B. D. Gaulin, S. Calder, and K. A. Ross, Dipolar spin ice regime proximate to an all-in-all-out néel ground state in the dipolar-octupolar pyrochlore Ce2Sn2O7, Phys. Rev. X 14, 011005 (2024).
  24. B. Gao, F. Desrochers, D. W. Tam, D. M. Kirschbaum, P. Steffens, A. Hiess, D. H. Nguyen, Y. Su, S.-W. Cheong, S. Paschen, Y. B. Kim, and P. Dai, Neutron scattering and thermodynamic evidence for emergent photons and fractionalization in a pyrochlore spin ice, Nat. Phys. 21, 1203 (2025).
  25. I. Živković, V. Favre, C. Salazar Mejia, H. O. Jeschke, A. Magrez, B. Dabholkar, V. Noculak, R. S. Freitas, M. Jeong, N. G. Hegde, L. Testa, P. Babkevich, Y. Su, P. Manuel, H. Luetkens, C. Baines, P. J. Baker, J. Wosnitza, O. Zaharko, Y. Iqbal, et al., Magnetic field induced quantum spin liquid in the two coupled trillium lattices of K2Ni2(SO4)3, Phys. Rev. Lett. 127, 157204 (2021).
  26. K. Boya, K. Nam, K. Kargeti, A. Jain, R. Kumar, S. K. Panda, S. M. Yusuf, P. L. Paulose, U. K. Voma, E. Kermarrec, K. H. Kim, and B. Koteswararao, Signatures of spin-liquid state in a 3D frustrated lattice compound KSrFe2(PO4)3 with S = 5/2, APL Mater. 10, 101103 (2022).
  27. W. Yao, Q. Huang, T. Xie, A. Podlesnyak, A. Brassington, C. Xing, R. S. D. Mudiyanselage, H. Wang, W. Xie, S. Zhang, M. Lee, V. S. Zapf, X. Bai, D. A. Tennant, J. Liu, and H. Zhou, Continuous spin excitations in the three-dimensional frustrated magnet K2Ni2(SO4)3, Phys. Rev. Lett. 131, 146701 (2023).
  28. M. G. Gonzalez, V. Noculak, A. Sharma, V. Favre, J.-R. Soh, A. Magrez, R. Bewley, H. O. Jeschke, J. Reuther, H. M. Rønnow, Y. Iqbal, and I. Živković, Dynamics of K2Ni2(SO4)3 governed by proximity to a 3D spin liquid model, Nat. Commun. 15, 7191 (2024).
  29. J. Khatua, S. Lee, G. Ban, M. Uhlarz, G. S. Murugan, R. Sankar, B. Hitti, G. Morris, K.-Y. Choi, and P. Khuntia, Magnetism and spin dynamics of the S=32 frustrated trillium lattice compound K2CrTi(PO4)3, Phys. Rev. B 109, 184432 (2024).
  30. R. Kolay, Q.-P. Ding, Y. Furukawa, A. A. Tsirlin, and R. Nath, Magnetic properties of the double trillium lattice antiferromagnet KBaCr2(PO4)3, Phys. Rev. B 110, 224405 (2024).
  31. L. Kubíčková, A. K. Weber, M. Panthöfer, S. Calder, and A. Möller, Cs2Fe2(MoO4)3-A strongly frustrated magnet with orbital degrees of freedom and magnetocaloric properties, Chem. Mater. 36, 7016 (2024).
  32. K. Boya, V. Sahu, R. Kumar, P. Paulose, and B. Koteswararao, Spin disorder state in a site-depleted 3D coupled trillium spin-lattice system Pb1.5Fe2(PO4)3, J. Magn. Magn. Mater. 629, 173302 (2025).
  33. S. J. Sebastian, Q.-P. Ding, A. A. Tsirlin, R. Nath, and Y. Furukawa, Short-range spin freezing in the double trillium lattice spin-liquid candidate KSrFe2(PO4)3 revealed via P31 NMR, Phys. Rev. B 112, L220406 (2025).
  34. S. J. Sebastian, S. S. Islam, R. Kolay, S. Mohanty, Q. P. Ding, Y. Skourski, J. Sichelschmidt, M. Baenitz, J. A. Krieger, T. J. Hicken, H. Luetkens, A. A. Tsirlin, Y. Furukawa, and R. Nath, Inhomogeneous dynamic state in the double trillium lattice antiferromagnet KBaFe2(PO4)3, arXiv:2511.07844
  35. J. Khatua and K.-Y. Choi, Frustration and chirality in three-dimensional trillium lattices: Insights and perspectives, J. Phys.: Condens. Matter 37, 483001 (2025).
  36. A. Magar, K. Somesh, M. P. Saravanan, J. Sichelschmidt, Y. Skourski, M. T. F. Telling, V. A. Ginga, A. A. Tsirlin, and R. Nath, Proximate spin-liquid behavior in the double trillium lattice antiferromagnet K2Co2(SO4)3, Phys. Rev. B 113, L020409 (2026).
  37. J. M. Hopkinson and H.-Y. Kee, Geometric frustration inherent to the trillium lattice, a sublattice of the B20 structure, Phys. Rev. B 74, 224441 (2006).
  38. S. V. Isakov, J. M. Hopkinson, and H.-Y. Kee, Fate of partial order on trillium and distorted windmill lattices, Phys. Rev. B 78, 014404 (2008).
  39. T. H. Berlin and M. Kac, The spherical model of a ferromagnet, Phys. Rev. 86, 821 (1952).
  40. H. E. Stanley, Spherical model as the limit of infinite spin dimensionality, Phys. Rev. 176, 718 (1968).
  41. M. Moshe and J. Zinn-Justin, Quantum field theory in the large N limit: A review, Phys. Rep. 385, 69 (2003).
  42. J. T. Chalker, P. C. W. Holdsworth, and E. F. Shender, Hidden order in a frustrated system: Properties of the Heisenberg Kagomé antiferromagnet, Phys. Rev. Lett. 68, 855 (1992).
  43. M. E. Zhitomirsky, Octupolar ordering of classical kagome antiferromagnets in two and three dimensions, Phys. Rev. B 78, 094423 (2008).
  44. G.-W. Chern and R. Moessner, Dipolar order by disorder in the classical Heisenberg antiferromagnet on the Kagome lattice, Phys. Rev. Lett. 110, 077201 (2013).
  45. J. D. Alzate-Cardona, D. Sabogal-Suárez, R. F. L. Evans, and E. Restrepo-Parra, Optimal phase space sampling for Monte Carlo simulations of Heisenberg spin systems, J. Phys.: Condens. Matter 31, 095802 (2019).
  46. J. Reuther and P. Wölfle, J1−J2 frustrated two-dimensional Heisenberg model: Random phase approximation and functional renormalization group, Phys. Rev. B 81, 144410 (2010).
  47. T. Müller, D. Kiese, N. Niggemann, B. Sbierski, J. Reuther, S. Trebst, R. Thomale, and Y. Iqbal, Pseudo-fermion functional renormalization group for spin models, Rep. Prog. Phys. 87, 036501 (2024).
  48. N. Niggemann, B. Sbierski, and J. Reuther, Frustrated quantum spins at finite temperature: Pseudo-Majorana functional renormalization group approach, Phys. Rev. B 103, 104431 (2021).
  49. B. Schneider, J. Reuther, M. G. Gonzalez, B. Sbierski, and N. Niggemann, Temperature flow in pseudo-Majorana functional renormalization for quantum spins, Phys. Rev. B 109, 195109 (2024).
  50. N. Niggemann, J. Reuther, and B. Sbierski, Quantitative functional renormalization for three-dimensional quantum Heisenberg models, SciPost Phys. 12, 156 (2022).
  51. Y. Schaden, M. G. Gonzalez, and J. Reuther, Phase diagram of the XXZ pyrochlore model from pseudo-Majorana functional renormalization group, Phys. Rev. B 111, 134442 (2025).
  52. M. Hering, V. Noculak, F. Ferrari, Y. Iqbal, and J. Reuther, Dimerization tendencies of the pyrochlore Heisenberg antiferromagnet: A functional renormalization group perspective, Phys. Rev. B 105, 054426 (2022).
  53. I. Hagymási, V. Noculak, and J. Reuther, Enhanced symmetry-breaking tendencies in the S=1 pyrochlore antiferromagnet, Phys. Rev. B 106, 235137 (2022).
  54. N. Niggemann, Temperature flow PMFRG, https://github.com/NilsNiggemann/PMFRG.jl/tree/TemperatureFlow (2023).
  55. J. Rehn, A. Sen, and R. Moessner, Fractionalized Z2 classical Heisenberg spin liquids, Phys. Rev. Lett. 118, 047201 (2017).
  56. A. Fancelli, R. Flores-Calderón, O. Benton, B. Lake, R. Moessner, and J. Reuther, Fragile spin liquid in three dimensions, Phys. Rev. B 111, 134413 (2025).
  57. T. E. Redpath and J. M. Hopkinson, Spin ice on the trillium lattice studied by Monte Carlo calculations, Phys. Rev. B 82, 014410 (2010).
  58. L. Pauling and G. W. Wheland, The nature of the chemical bond. V. The quantum‐mechanical calculation of the resonance energy of benzene and naphthalene and the hydrocarbon free radicals, J. Chem. Phys. 1, 362 (1933).
  59. R. Moessner and S. L. Sondhi, Three-dimensional resonating-valence-bond liquids and their excitations, Phys. Rev. B 68, 184512 (2003).
  60. D. A. Huse, W. Krauth, R. Moessner, and S. L. Sondhi, Coulomb and liquid dimer models in three dimensions, Phys. Rev. Lett. 91, 167004 (2003).
  61. R. R. P. Singh and J. Oitmaa, Corrections to Pauling residual entropy and single tetrahedron based approximations for the pyrochlore lattice Ising antiferromagnet, Phys. Rev. B 85, 144414 (2012).
  62. S. D. Pace, S. C. Morampudi, R. Moessner, and C. R. Laumann, Emergent fine structure constant of quantum spin ice is large, Phys. Rev. Lett. 127, 117205 (2021).
  63. D. A. Garanin and B. Canals, Classical spin liquid: Exact solution for the infinite-component antiferromagnetic model on the kagomé lattice, Phys. Rev. B 59, 443 (1999).
  64. R. Moessner and J. T. Chalker, Low-temperature properties of classical geometrically frustrated antiferromagnets, Phys. Rev. B 58, 12049 (1998).
  65. M. Gonzalez, Data for figures in “Spin liquids on the tetratrillium lattice”, Zenodo (2026), doi: 10.5281/zenodo.18385092.

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