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Absence of magnetic order in epitaxial RuO2 revealed by x-ray linear dichroism

Siyu Wang1,*, Chao Wang1,*, Yanan Yuan1, Jiangxiao Li1, Fangfang Pei1, Daxiang Liu1, Chunyu Qin1, Jiefeng Cao2, Yamei Wang2 et al.

Tianye Wang3, Jiayu Liu1, Ji-Eun Lee3, Guanhua Zhang4, Christoph Klewe5, Chenchao Yu6, Fan Zhang7, Dongsheng Song3, Kai Chen1, Weisheng Zhao5, Dawei Shen1, Ziqiang Qiu3, Mengmeng Yang6,†, Bin Hong7,‡, and Qian Li1,§

  • *These authors contributed equally to this work.
  • †Contact author: mmyang@ahu.edu.cn
  • ‡Contact author: binhong@buaa.edu.cn
  • §Contact author: liqian89@ustc.edu.cn

Phys. Rev. B 113, 024439 – Published 30 January, 2026

DOI: https://doi.org/10.1103/vqrj-2trm

Abstract

Recently the topic of altermagnetism has attracted tremendous attention, and RuO2 has been demonstrated to be one of the most promising altermagnetic candidates. However, disputes still remain on the existence of magnetic order in RuO2. Here in this work, we employ x-ray linear dichroism (XLD), a widely utilized technique for characterizing antiferromagnets, in conjunction with photoemission electron microscopy and multiple scattering calculation to provide clear evidence of the absence of magnetic order in epitaxial RuO2 films. The observed XLD signal is nearly invariant with temperature and independent of cooling-field direction, in stark contrast to the substantial magnetic-order-related XLD signal predicted by multiple scattering calculation. This finding strongly suggests a nonmagnetic origin for RuO2. Furthermore, we observed significantly distinct XLD signals at the Ru M3 and O K edges in RuO2 films grown on TiO2 substrate with different surface orientations, which can be attributed to the low-symmetry crystal field. These results unequivocally demonstrate the absence of magnetic order in RuO2 and establish XLD measurement as a robust technique for probing the low-symmetry magnetic materials.

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