Origin of ferromagnetism and trends in Berry curvature driven anomalous Hall conductivity in the metallic rare-earth antimonides ( = La, Ce, Nd)
Phys. Rev. B 112, 094427 – Published 12 September, 2025
DOI: https://doi.org/10.1103/vqb7-vz11
Abstract
Employing a combination of first-principles calculations and an ab initio derived model Hamiltonian study, we investigate the electronic and magnetic properties of the rare-earth antimonides , and . Our findings indicate that the long-range ferromagnetic order in these metallic compounds originates from a kinetic energy-driven double exchange mechanism, first proposed in the context of double perovskite compound . The calculated magnetic transition temperatures are in reasonable agreement with the measured values. The spin-orbit coupled band structure of the studied compounds reveals nontrivial topology, hosting multiple Weyl point crossings. The number of these crossings increases in moving from to to , assisted by the lowering of the states in nonzero rare-earth compounds. The calculated anomalous Hall conductivity captures experimentally observed large anomalous Hall conductivity in these compounds, and the trend between , and . Our study provides a microscopic understanding of the trend.