Decisive role of an extra Fe sublattice: Frustration, criticality, and skyrmions in the van der Waals ferromagnets versus
Phys. Rev. B 113, 214451 – Published 23 June, 2026
DOI: https://doi.org/10.1103/v9rm-l6vb
Abstract
The van der Waals magnets and , chemically similar yet magnetically distinct, provide an ideal platform for probing how structural complexity governs emergent magnetic order, anisotropy, and topological textures. does not host skyrmions, whereas does, raising fundamental questions about the roles of inversion symmetry, frustration, and exchange interactions. Through comprehensive magnetization, susceptibility, and critical exponent analysis, we demonstrate that magnetic frustration, absent in , is crucial in . The extra sublattice in breaks inversion symmetry, introduces competing exchange, and yields a significant frustration parameter 3.8. Critical exponent analysis reveals field-driven crossover from a mean field to a 2D-Heisenberg class with increasing field in , whereas field-driven crossover from a frustrated 3D-Heisenberg class () at low fields reveals a conventional 3D-Heisenberg class () at high fields in . Our results establish magnetic frustration, rather than the Dzyaloshinskii-Moriya interaction alone, as the key ingredient stabilizing skyrmionic phases, offering a design principle for topological spin textures in layered van der Waals magnets. We show here that an extra sublattice in is essentially responsible for most of the differences in magnetic properties between and .