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    Grüneisen parameter of dense fluid helium at gigapascal pressures and 300 K

    Jun Kong1,2,*, Kaiyuan Shi1,*, Xin Zhang1,*, Jiaqing Zhang3, Zhaoxu Du1, Xingbang Dong1, Haotian Yang1, Lei Su1,3,†, Xiao Dong2,‡ et al.

    Eugene Gregoryanz1,3,4,5,§ and Ho-kwang Mao1,3,∥

    • 1Center for High Pressure Science and Technology Advanced Research, Beijing 100193, People's Republic of China
    • 2Key Laboratory of Weak-Light Nonlinear Photonics and School of Physics, Nankai University, Tianjin 300071, People's Republic of China
    • 3Shanghai Key Laboratory of Material Frontiers Research in Extreme Environments, Shanghai Advanced Research in Physical Sciences, Shanghai 201203, People's Republic of China
    • 4Key Laboratory of Materials Physics, Institute of Solid State Physics, HFIPS, Chinese Academy of Sciences (CAS), Hefei, People's Republic of China
    • 5School of Physics and Centre for Science at Extreme Conditions, University of Edinburgh, Edinburgh, United Kingdom

    • *These authors contributed equally to this work.
    • †Contact author: lei.su@hpstar.ac.cn
    • ‡Contact author: xiao.dong@nankai.edu.cn
    • §Contact author: e.gregoryanz@sharps.ac.cn
    • ∥Contact author: maohk@hpstar.ac.cn

    Phys. Rev. B 114, 024109 – Published 27 July, 2026

    DOI: https://doi.org/10.1103/tzvf-qmx9

    Abstract

    Utilizing dynamic diamond anvil cell combined with time-resolved temperature-pressure multichannel measurement system, we have measured fluid helium-4′s Grüneisen parameter between 6 and 11 GPa at around 300 K. The measurements yielded the high-pressure volumetric thermal expansion coefficient, with pressure dependence similar to that of dense hydrogen and argon. Unlike the case of low-temperature fluid helium, the unique pressure dependence of the Grüneisen parameter with pressure at room temperature and its jump near the fluid-solid transition may serve as an indicator of localized atomic aggregation of fluid helium under high pressure. This work provides crucial experimental constraints for understanding the thermodynamic behavior and microscopic interactions in dense fluid helium, offering new insights into the high-pressure physics of simple quantum fluids.

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