Correlation-driven lattice anharmonicity and anomalous thermal transport in the kagome metal
Phys. Rev. B 114, 045128 – Published 28 July, 2026
DOI: https://doi.org/10.1103/t6m3-fy63
Abstract
Lattice thermal transport in metals is traditionally described under the assumption that a highly mobile electron gas efficiently screens ionic displacements, resulting in a predominantly harmonic interatomic potential. Here, we show that strong electron-electron correlations can profoundly disrupt this screening mechanism, promoting intrinsic phonon scattering in the kagome metal . By comparing orbital-resolved band calculations with high-resolution angle-resolved photoemission spectroscopy, we identify a strongly correlated Cu flat band and extract an effective Hubbard interaction of . We demonstrate that this on-site Coulomb interaction localizes the Cu valence charge, indicating a reduced local charge response to ionic displacements. As a consequence of the reduced electronic screening, the lattice potential and phonon spectrum are strongly renormalized, substantially expanding the three-phonon scattering phase space. Consequently, electronic correlations alone intrinsically suppress the room-temperature lattice thermal conductivity by approximately 53%. These findings identify correlation-driven anharmonicity as a significant, nonstructural factor for suppressing thermal conductivity, thereby providing a possible route to mitigate the conventional trade-off between enhanced phonon scattering and high electronic mobility.