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    Correlation-driven lattice anharmonicity and anomalous thermal transport in the kagome metal CaCu5

    Tongrui Li1,*, Zhicheng Jiang1,*, Peng Wu2,*,†, Jian Yuan3,*, Jie Sun4, Lidong Zhang1, Zhengtai Liu5,6, Yanfeng Guo3,7,‡, Dawei Shen1,§ et al.

    Zhe Sun1,∥

    • *These authors contributed equally to this work.
    • †Contact author: pengwoo@ncepu.edu.cn
    • ‡Contact author: guoyf@shanghaitech.edu.cn
    • §Contact author: daweishen@ustc.edu.cn
    • ∥Contact author: zsun@ustc.edu.cn

    Phys. Rev. B 114, 045128 – Published 28 July, 2026

    DOI: https://doi.org/10.1103/t6m3-fy63

    Abstract

    Lattice thermal transport in metals is traditionally described under the assumption that a highly mobile electron gas efficiently screens ionic displacements, resulting in a predominantly harmonic interatomic potential. Here, we show that strong electron-electron correlations can profoundly disrupt this screening mechanism, promoting intrinsic phonon scattering in the kagome metal CaCu5. By comparing orbital-resolved band calculations with high-resolution angle-resolved photoemission spectroscopy, we identify a strongly correlated Cu 3d flat band and extract an effective Hubbard interaction of U≈3eV. We demonstrate that this on-site Coulomb interaction localizes the Cu 3d valence charge, indicating a reduced local charge response to ionic displacements. As a consequence of the reduced electronic screening, the lattice potential and phonon spectrum are strongly renormalized, substantially expanding the three-phonon scattering phase space. Consequently, electronic correlations alone intrinsically suppress the room-temperature lattice thermal conductivity by approximately 53%. These findings identify correlation-driven anharmonicity as a significant, nonstructural factor for suppressing thermal conductivity, thereby providing a possible route to mitigate the conventional trade-off between enhanced phonon scattering and high electronic mobility.

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