Export citation

Export citation

Choose format for download:

Download Citation

    Entropy landscape and field-tuned thermodynamics of the large-spin Shastry-Sutherland magnet Eu2MgSi2O7

    Huanpeng Bu1, Han Ge1, Fangli Li1, Lei Xu2, Jiayue Yuan1, Tiantian Li1,3, Junzhe Liu1, Jian Chen1, Ying Fu1,4 et al.

    Nan Zhao5,6, Zhongwen Ouyang7, Ping Miao5,6, Jieming Sheng8, and Liusuo Wu1,4,9,*

    • *Contact author: wuls@sustech.edu.cn

    Phys. Rev. B 113, 214447 – Published 22 June, 2026

    DOI: https://doi.org/10.1103/sq69-y3j5

    Abstract

    We present a comprehensive study of the low-temperature magnetism and field-tuned thermodynamics of the layered Shastry-Sutherland compound Eu2MgSi2O7. Eu2+ ions (4f7, S=7/2) form a quasi-two-dimensional orthogonal-dimer network, realizing a large-spin Heisenberg system on a Shastry-Sutherland geometry that is prone to geometric frustration. Magnetic susceptibility and magnetization measurements reveal nearly isotropic Eu2+ moments with weak antiferromagnetic interactions. Specific-heat data uncover a primary long-range ordered state at TN1=0.8K and a second anomaly near TN2=1.0K that is rapidly suppressed by magnetic field, suggesting that it is more field sensitive and may not correspond to an independent thermodynamic phase transition. By separating the magnetic heat capacity, we determine the full magnetic-entropy surface Sm(T,B), which captures the smooth field-driven evolution from the ordered state to a correlated and eventually polarized paramagnetic regime. The resulting isentropic trajectories demonstrate efficient adiabatic demagnetization, allowing cooling from 1.5–3.1 K at 5 T to minimum temperatures of 0.21–0.50 K. Comparison with the benchmark refrigerant Gd3Ga5O12 shows that Eu2MgSi2O7 exhibits enhanced sub-Kelvin magnetic heat-storage capacity, reflecting its large accessible spin entropy and weak interactions. These results establish Eu2MgSi2O7 as a rare example of a Eu-based frustrated magnet that combines weak interactions, a well-resolved low-temperature ordered state, and tunable thermodynamics suitable for sub-Kelvin cryogenic applications.

    Physics Subject Headings (PhySH)

    Authorization Required

    We need you to provide your credentials before accessing this content.

    References (Subscription Required)

    Outline

    Information

    Sign In to Your Journals Account

    Filter

    Filter

    Article Lookup

    Enter a citation