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    Electronic topological transition in zinc under shock compression revealed by electrical resistivity measurements

    Zhenning Wang1,2, Yifeng Zhang1, Feng Gao3, Xilong Dou4, Bo Gan1,5,*, and Kaile Tang1

    • *Contact author: ganbo@scu.edu.cn

    Phys. Rev. B 112, 195130 – Published 24 November, 2025

    DOI: https://doi.org/10.1103/s3h3-6198

    Abstract

    Electronic topological transitions (ETTs) are characterized by abrupt changes in Fermi-surface topology, which can lead to pronounced anomalies in the physical properties of transition metals under high pressure-temperature (P−T) conditions. Zinc (Zn), a group-IIB transition metal with a fully occupied 3d shell and a highly anisotropic hexagonal structure, has been proposed to undergo a Lifshitz-type ETT at ∼6–10 GPa. However, its existence and thermodynamic characteristics at high P-T remained unresolved. Here, we investigate the longitudinal sound velocity of Zn up to ∼11 GPa and the electrical resistivity up to ∼20 GPa and ∼430 K under shock compression, using the reverse-impact configuration and four-probe technique, respectively. The sound velocity evolves smoothly with pressure across the investigated range, with no detectable elastic or structural anomalies. In contrast, the electrical resistivity exhibits a notable slope change at 14(1) GPa, followed by a steeper pressure dependence. This anomaly aligns with the pressure-induced ETT identified in static compression studies, but occurs at a higher critical pressure under shock loading. This shift highlights the influence of shock-elevated temperature and dynamic compression in delaying the onset of the transition. The more rapid increase in resistivity within the ETT is attributed to Fermi-surface reconstruction, which modifies band curvature, carrier effective mass, and scattering rates. These results provide strong experimental evidence for the ETT in Zn under high P−T conditions, and demonstrate that dynamic resistivity measurements serve as a sensitive probe of subtle electronic transitions in transition metals.

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