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    Kibble-Zurek dynamics across the first-order quantum transitions of quantum Ising chains in the thermodynamic limit

    Andrea Pelissetto1, Davide Rossini2, and Ettore Vicari3,*

    • *Contact author: ettore.vicari@unipi.it

    Phys. Rev. B 112, 104309 – Published 9 September, 2025

    DOI: https://doi.org/10.1103/qwnj-r63c

    Abstract

    We study the out-of-equilibrium Kibble-Zurek (KZ) dynamics in quantum Ising chains in a transverse field, driven by a time-dependent longitudinal field h(t)=t/ts (ts is the timescale of the protocol), across their first-order quantum transitions (FOQTs) at h=0. The KZ protocol starts at time ti<0 from the negatively magnetized ground state for hi=ti/ts<0. Then, the system evolves unitarily up to a time tf>0, such that the magnetization of the state at time tf is positive. In finite-size systems, the KZ dynamics develops out-of-equilibrium finite-size scaling (OFSS) behaviors. Their scaling variables depend either exponentially or with a power law on the size, depending on the boundary conditions (BC). The OFSS functions can be computed in effective models restricted to appropriate low-energy (magnetized and/or kink) states. The KZ scaling behavior drastically changes in the thermodynamic limit (TL), defined as the infinite-size limit keeping t and ts fixed, which appears substantially unrelated with the OFSS regime, because it involves higher-energy multikink states, which are irrelevant in the OFSS limit. The numerical analyses of the KZ dynamics in the TL show the emergence of a quantum spinodal-like scaling behavior at the FOQTs for all considered BC, which is independent of the BC. The longitudinal magnetization changes sign at h(t)=h★>0, where h★ decreases with increasing ts, as h★∼1/lnts. Moreover, in the large-ts limit, the time dependence of the magnetization is described by a universal function of Ω=t/τs, with τs=ts/lnts.

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