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    Probing intervalley coupling via exciton hybridization in a charge-tunable GaAs/AlAs quantum dot

    Arnault Raymond*, Paola Atkinson, Antoine Chapuis, Savvas Germanis, Florent Margaillan, Mathieu Bernard, Valia Voliotis, and Benoit Eble†

    • *Contact author: araymond@insp.jussieu.fr
    • †Contact author: benoit.eble@insp.jussieu.fr

    Phys. Rev. B 112, 125302 – Published 16 September, 2025

    DOI: https://doi.org/10.1103/qlvx-wpbf

    Abstract

    We study a type-II GaAs/AlAs quantum dot system that enables intervalley coupling between electronic states in the Γ and Xz valleys, probed optically at the single-dot level. This structure intrinsically supports both direct and indirect excitons, with their spatial separation tunable via an external electric field. Stark shift spectroscopy reveals a clear double anticrossing in the neutral exciton line as a direct signature of intervalley coupling. Experimental observations, including measurements of static dipole moments and electron g factors, confirm electron confinement within the AlAs barrier and highlight the involvement of barrier-localized states. We further propose that these states may contribute to the formation of multicharged excitonic complexes. A simplified model allows us to estimate the interfacial coupling strength from the measured anticrossing amplitudes.

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