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    Incomplete softening of the antiferromagnetic resonance mode at the spin-reorientation transition in multiferroic GdFe3(BO3)4

    I. N. Khoroshiy1,2, S. A. Skorobogatov1,2, S. E. Nikitin1, I. A. Gudim1, V. R. Titova1, and A. I. Pankrats1,2

    Phys. Rev. B 112, 224421 – Published 11 December, 2025

    DOI: https://doi.org/10.1103/qlq6-b67j

    Abstract

    The multiferroic ferroborate GdFe3(BO3)4 with huntite-type structure exhibits magnetic ordering below TN=38 K and contains two magnetic subsystems associated with Gd and Fe ions. Competing anisotropies of these subsystems drive a spin-reorientation transition at TSR=10.7 K, switching the ground state from easy-axis to easy-plane. Using antiferromagnetic resonance, we investigate the spin dynamics across this transition. The observed incomplete softening of a magnon mode during both field- and temperature-induced spin-reorientation transitions indicates the first-order nature of the phase transition, which is accompanied by a discontinuous jump in the effective anisotropy field. We reproduce this behavior using a simple model that attributes the jump in the anisotropy field to the presence of an effective fourth-order anisotropy constant, responsible for the discontinuous character of the transition. Remarkably, for in-plane magnetic fields, we identify a new AFMR mode that persists from 12 K up to TN. This mode likely corresponds to the dynamics of a long-period incommensurate state, previously detected by resonant elastic x-ray scattering.

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