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    Theoretical study on ambient-pressure superconductivity in La3Ni2O7 thin films: Structural analysis, model construction, and robustness of s±-wave pairing

    Kensei Ushio1, Shu Kamiyama2, Yuto Hoshi1, Ryota Mizuno3, Masayuki Ochi2,3,*, Kazuhiko Kuroki2,†, and Hirofumi Sakakibara1,4,‡

    • 1Faculty of Engineering, Tottori University, 4-101 Koyama-cho Minami, Tottori, Tottori 680-8552, Japan
    • 2Department of Physics, University of Osaka, 1-1 Machikaneyama-cho, Toyonaka, Osaka 560-0043, Japan
    • 3Forefront Research Center, University of Osaka, 1-1 Machikaneyama-cho, Toyonaka, Osaka 560-0043, Japan
    • 4Advanced Mechanical and Electronic System Research Center (AMES), Tottori University, 4-101 Koyama-cho Minami, Tottori, Tottori 680-8552, Japan

    • *Contact author: ochi@presto.phys.sci.osaka-u.ac.jp
    • †Contact author: kuroki@presto.phys.sci.osaka-u.ac.jp
    • ‡Contact author: sakakibara@tottori-u.ac.jp

    Phys. Rev. B 114, 014501 – Published 1 July, 2026

    DOI: https://doi.org/10.1103/ql1x-2k9q

    Abstract

    We theoretically study ambient-pressure superconductivity in thin films of La3Ni2O7. We construct model Hamiltonians adopting the crystal structure theoretically determined by fixing the in-plane lattice constant to those substrates examined in the experiment. We also construct a model based on the experimentally determined lattice structure. To the models obtained we apply the fluctuation exchange approximation, which takes into account the full momentum and frequency dependencies of the Green function and the pairing interaction. We find that the electronic structure, including the presence/absence of the so-called γ pocket (the Fermi surface originating from the top of the d3z2−r2 bonding band), depends on the crystal structure adopted and/or the presence/absence of +U correction in the band structure calculation. Nonetheless, s±-wave pairing symmetry remains robust regardless of these details in the band structure. The robustness of the s±-wave pairing is mainly due to the fact that it is mediated by finite-energy spin fluctuations, which are insensitive to the details of the Fermi surface topology and give rise to a nearly momentum-independent gap function for the interlayer d3z2−r2 pairing in the orbital representation. On the other hand, Tc being halved from that of the pressurized bulk can only be understood by adopting the model with small |t⊥| derived from the experimentally determined crystal structure, at least within the present FLEX approach, although there may remain some other possibilities beyond this approach for the origin of the reduced Tc.

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