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    Spin waves in Na2Co2TeO6 studied by high-frequency/high-field ESR: Successes and failures of the triple-q model

    Luca Bischof1,*, Jan Arneth1, Raju Kalaivanan2, Raman Sankar2, Kwang-Yong Choi3, and Rüdiger Klingeler1,†

    • *Contact author: luca.bischof@kip.uni-heidelberg.de
    • †Contact author: klingeler@kip.uni-heidelberg.de

    Phys. Rev. B 112, 104406 – Published 3 September, 2025

    DOI: https://doi.org/10.1103/qk2w-hx49

    Abstract

    The Kitaev candidate material Na2Co2TeO6 is proposed to be proximate to a quantum spin liquid state but a suitable spin model and the nature of its ground states are still under debate. Our high-frequency/high-field electron spin resonance spectroscopy studies of Na2Co2TeO6 single crystals under in-plane and out-of-plane magnetic fields elucidate the ground state by investigating its low-energy spin wave excitations. Several excitation modes are observed in the low-field phase and in the phases induced by B∥a*. In addition, the spectra exhibit a frequency-independent feature at the phase boundary connected to the putative quantum phase transition. For magnetic fields applied along the c axis, the observation of three distinct spin wave modes in the antiferromagnetic (AFM) ground state reveals a previously unresolved splitting of the zero-field excitation gap into Δ=211GHz and Δ2=237GHz. The softening of one of these modes evidences a field-induced phase transition at Bc1=4.7T, which is corroborated by a clear anomaly in the isothermal magnetization. Spin wave calculations based on the extended Heisenberg-Kitaev model exclude a zigzag ground state of the AFM phase. A triple-q spin configuration correctly predicts two spin wave modes but fails to reproduce the softening mode. Our analysis shows that the triple-q ground state model of Na2Co2TeO6 is incomplete and suggests the relevance of interlayer interactions.

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