Reuse & Permissions

It is not necessary to obtain permission to reuse this article or its components as it is available under the terms of the Creative Commons Attribution 4.0 International license. This license permits unrestricted use, distribution, and reproduction in any medium, provided attribution to the author(s) and the published article's title, journal citation, and DOI are maintained. Please note that some figures may have been included with permission from other third parties. It is your responsibility to obtain the proper permission from the rights holder directly for these figures.

Export citation

Export citation

Choose format for download:

Download Citation
  • Editors' Suggestion
  • Open Access

Three-dimensional spin-orbital liquids

Anna Sandberg1, Lukas Rødland2, and Maria Hermanns1,*

  • *Contact author: maria.hermanns@fysik.su.se

Phys. Rev. B 113, 235120 – Published 12 June, 2026

DOI: https://doi.org/10.1103/qhfj-m9dl

Abstract

Spin-orbital liquids provide an exactly solvable route to three-dimensional Z2 quantum spin liquids beyond the original Kitaev setting. Built from higher-dimensional Clifford-algebra representations, spin-orbital Hamiltonians can be realized on both three- and four-coordinated lattices, giving rise to phases with ν=3 and 2 itinerant Majorana flavors, respectively. We demonstrate that these models host a rich set of gapless Majorana metals, characterized, in particular, by topological Fermi surfaces, nodal lines, and Weyl semimetal phases. We analyze the stability of these structures under physically motivated perturbations and identify generic splitting patterns and topological transitions driven by symmetry breaking and flavor mixing. This yields a unified organizing framework for three-dimensional Majorana metals in fractionalized spin liquids.

View figure in article

Physics Subject Headings (PhySH)

Article Text

References (59)

  1. P. W. Anderson, Resonating valence bonds: A new kind of insulator? Mater. Res. Bull. 8, 153 (1973).
  2. X.-G. Wen, Quantum orders and symmetric spin liquids, Phys. Rev. B 65, 165113 (2002).
  3. L. Balents, Spin liquids in frustrated magnets, Nature (London) 464, 199 (2010).
  4. C. Broholm, R. J. Cava, S. A. Kivelson, D.-H. Lee, B. Normand, and T. Senthil, Quantum spin liquids, Science 367, eaay0668 (2020).
  5. J. Knolle and R. Moessner, A field guide to spin liquids, Annu. Rev. Condens. Matter Phys. 10, 451 (2019).
  6. Y. Zhou, K. Kanoda, and T.-K. Ng, Quantum spin liquid states, Rev. Mod. Phys. 89, 025003 (2017).
  7. L. Savary and L. Balents, Quantum spin liquids: A review, Rep. Prog. Phys. 80, 016502 (2017).
  8. A. Y. Kitaev, Fault-tolerant quantum computation by anyons, Ann. Phys. 303, 2 (2003).
  9. M. A. Levin and X.-G. Wen, String-net condensation: A physical mechanism for topological phases, Phys. Rev. B 71, 045110 (2005).
  10. A. Kitaev, Anyons in an exactly solved model and beyond, Ann. Phys. 321, 2 (2006).
  11. R. Moessner and S. L. Sondhi, Resonating valence bond phase in the triangular lattice quantum dimer model, Phys. Rev. Lett. 86, 1881 (2001).
  12. G. Baskaran, S. Mandal, and R. Shankar, Exact results for spin dynamics and fractionalization in the Kitaev model, Phys. Rev. Lett. 98, 247201 (2007).
  13. J. Knolle, D. L. Kovrizhin, J. T. Chalker, and R. Moessner, Dynamics of a two-dimensional quantum spin liquid: Signatures of emergent Majorana fermions and fluxes, Phys. Rev. Lett. 112, 207203 (2014).
  14. J. Knolle, G.-W. Chern, D. L. Kovrizhin, R. Moessner, and N. B. Perkins, Raman scattering signatures of Kitaev spin liquids in A2IrO3 iridates with A = Na or Li, Phys. Rev. Lett. 113, 187201 (2014).
  15. M. Kanega, T. N. Ikeda, and M. Sato, Linear and nonlinear optical responses in Kitaev spin liquids, Phys. Rev. Res. 3, L032024 (2021).
  16. H. Yao and S. A. Kivelson, Exact chiral spin liquid with non-Abelian anyons, Phys. Rev. Lett. 99, 247203 (2007).
  17. S. Yang, D. L. Zhou, and C. P. Sun, Mosaic spin models with topological order, Phys. Rev. B 76, 180404(R) (2007).
  18. S. Mandal and N. Surendran, Exactly solvable Kitaev model in three dimensions, Phys. Rev. B 79, 024426 (2009).
  19. M. Hermanns and S. Trebst, Quantum spin liquid with a Majorana Fermi surface on the three-dimensional hyperoctagon lattice, Phys. Rev. B 89, 235102 (2014).
  20. K. O'Brien, M. Hermanns, and S. Trebst, Classification of gapless Z2 spin liquids in three-dimensional Kitaev models, Phys. Rev. B 93, 085101 (2016).
  21. T. Eschmann, P. A. Mishchenko, T. A. Bojesen, Y. Kato, M. Hermanns, Y. Motome, and S. Trebst, Thermodynamics of a gauge-frustrated Kitaev spin liquid, Phys. Rev. Res. 1, 032011(R) (2019).
  22. M. G. Yamada, V. Dwivedi, and M. Hermanns, Crystalline Kitaev spin liquids, Phys. Rev. B 96, 155107 (2017).
  23. H. Yao, S.-C. Zhang, and S. A. Kivelson, Algebraic spin liquid in an exactly solvable spin model, Phys. Rev. Lett. 102, 217202 (2009).
  24. S. Ryu, Three-dimensional topological phase on the diamond lattice, Phys. Rev. B 79, 075124 (2009).
  25. C. Wu, D. Arovas, and H.-H. Hung, Γ-matrix generalization of the Kitaev model, Phys. Rev. B 79, 134427 (2009).
  26. V. Chua, H. Yao, and G. A. Fiete, Exact chiral spin liquid with stable spin Fermi surface on the kagome lattice, Phys. Rev. B 83, 180412(R) (2011).
  27. R. Nakai, S. Ryu, and A. Furusaki, Time-reversal symmetric Kitaev model and topological superconductor in two dimensions, Phys. Rev. B 85, 155119 (2012).
  28. F. Wang and A. Vishwanath, Z2 spin-orbital liquid state in the square lattice Kugel-Khomskii model, Phys. Rev. B 80, 064413 (2009).
  29. P. Corboz, M. Lajkó, A. M. Läuchli, K. Penc, and F. Mila, Spin-orbital quantum liquid on the honeycomb lattice, Phys. Rev. X 2, 041013 (2012).
  30. S. Chulliparambil, U. F. P. Seifert, M. Vojta, L. Janssen, and H.-H. Tu, Microscopic models for Kitaev's sixteenfold way of anyon theories, Phys. Rev. B 102, 201111(R) (2020).
  31. S. Chulliparambil, L. Janssen, M. Vojta, H.-H. Tu, and U. F. P. Seifert, Flux crystals, Majorana metals, and flat bands in exactly solvable spin-orbital liquids, Phys. Rev. B 103, 075144 (2021).
  32. F. L. Pedrocchi, S. Chesi, and D. Loss, Physical solutions of the Kitaev honeycomb model, Phys. Rev. B 84, 165414 (2011).
  33. E. H. Lieb, Flux phase of the half-filled band, Phys. Rev. Lett. 73, 2158 (1994).
  34. J. Nasu, T. Kaji, K. Matsuura, M. Udagawa, and Y. Motome, Finite-temperature phase transition to a quantum spin liquid in a three-dimensional Kitaev model on a hyperhoneycomb lattice, Phys. Rev. B 89, 115125 (2014).
  35. T. Eschmann, P. A. Mishchenko, K. O'Brien, T. A. Bojesen, Y. Kato, M. Hermanns, Y. Motome, and S. Trebst, Thermodynamic classification of three-dimensional Kitaev spin liquids, Phys. Rev. B 102, 075125 (2020).
  36. P. A. Mishchenko, Y. Kato, K. O'Brien, T. A. Bojesen, T. Eschmann, M. Hermanns, S. Trebst, and Y. Motome, Chiral spin liquids with crystalline Z2 gauge order in a three-dimensional Kitaev model, Phys. Rev. B 101, 045118 (2020).
  37. Fundamental plaquettes are those that cannot be built up by smaller plaquettes.
  38. J. Nasu, M. Udagawa, and Y. Motome, Vaporization of Kitaev spin liquids, Phys. Rev. Lett. 113, 197205 (2014).
  39. Band degeneracies (former choice) or zero modes (latter choice) need to be handled carefully.
  40. In [24, 27], an alternative TR symmetry was considered for the ν=2 case, involving a combination of T with a rotation of the spin degrees of freedom. In the Majorana representation, this changes the symmetry class to DIII, yielding a Z2 invariant in two dimensions and a Z invariant in three dimensions. Such a symmetry construction is not possible for the ν=3 model.
  41. J. Chaloupka and G. Khaliullin, Hidden symmetries of the extended Kitaev-Heisenberg model: Implications for the honeycomb-lattice iridates A2IrO3, Phys. Rev. B 92, 024413 (2015).
  42. G. Khaliullin and S. Okamoto, Theory of orbital state and spin interactions in ferromagnetic titanates, Phys. Rev. B 68, 205109 (2003).
  43. I. Kimchi and A. Vishwanath, Kitaev-Heisenberg models for iridates on the triangular, hyperkagome, kagome, fcc, and pyrochlore lattices, Phys. Rev. B 89, 014414 (2014).
  44. Note, however, that the resulting 1D chains are different for each of the Majorana flavors.
  45. Quartic perturbations, on the other hand, can gap the Majorana FS of the isotropic system to nodal lines, which in turn are protected by TR [56].
  46. B. Bradlyn, J. Cano, Z. Wang, M. Vergniory, C. Felser, R. J. Cava, and B. A. Bernevig, Beyond Dirac and Weyl fermions: Unconventional quasiparticles in conventional crystals, Science 353, aaf5037 (2016).
  47. I. Kimchi, J. G. Analytis, and A. Vishwanath, Three-dimensional quantum spin liquids in models of harmonic-honeycomb iridates and phase diagram in an infinite-D approximation, Phys. Rev. B 90, 205126 (2014).
  48. E. K.-H. Lee, R. Schaffer, S. Bhattacharjee, and Y. B. Kim, Heisenberg-Kitaev model on the hyperhoneycomb lattice, Phys. Rev. B 89, 045117 (2014).
  49. T. Takayama, A. Kato, R. Dinnebier, J. Nuss, H. Kono, L. S. I. Veiga, G. Fabbris, D. Haskel, and H. Takagi, Hyperhoneycomb iridate β−Li2IrO3 as a platform for Kitaev magnetism, Phys. Rev. Lett. 114, 077202 (2015).
  50. H. Takagi, T. Takayama, G. Jackeli, G. Khaliullin, and S. E. Nagler, Concept and realization of Kitaev quantum spin liquids, Nat. Rev. Phys. 1, 264 (2019).
  51. Note that the lattice has two types of bonds that are not connected by any symmetry—those constituting the spirals and those connecting them. Without loss of generality, we will set the coupling constants identical for both types.
  52. We note that in certain parameter regimes—in particular for Γ′<0.5, K=Γ=0—the system can exhibit ringlike low-energy features that, however, are not nodal lines. Rather, the low-energy features originate from the presence of six chargeless zero-modes on the ring, with a very flat but nonzero dispersion connecting them.
  53. M. O'keeffe and N. Brese, Uninodal 4-connected 3D nets. I. Nets without 3-or 4-rings, Found. Crystallogr. 48, 663 (1992).
  54. In our numerical simulations, we considered values up to κ=5.
  55. The mirror planes of the honeycomb lattice become glide-mirrors for the layered honeycomb. The latter are of no use in Lieb's theorem.
  56. M. Hermanns, S. Trebst, and A. Rosch, Spin-Peierls instability of three-dimensional spin liquids with Majorana Fermi surfaces, Phys. Rev. Lett. 115, 177205 (2015).
  57. K. Momma and F. Izumi, VESTA 3 for three-dimensional visualization of crystal, volumetric and morphology data, J. Appl. Crystallogr. 44, 1272 (2011).
  58. S. Danisch and J. Krumbiegel, Makie.jl: Flexible high-performance data visualization for Julia, J. Open Source Software 6, 3349 (2021).
  59. A. Sandberg, L. Rødland, and M. Hermanns, Data3DSOLs [Figure data] (2026), GitHub https://github.com/sandbergsanna/Data3DSOLs.

Outline

Information

Sign In to Your Journals Account

Filter

Filter

Article Lookup

Enter a citation