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    Comment on “Doping-induced canted ferromagnetism in pyrochlore titanate”

    Alexei A. Belik

    Phys. Rev. B 114, 196401 – Published 6 October, 2026

    DOI: https://doi.org/10.1103/qb5d-pp58

    Abstract

    In a recent paper [D. Sahu et al., Phys. Rev. B 112, 144412 (2025)], claims were made about (1) the appearance of noncoplanar and ferromagnetic ordering below 146 K in solid solutions Y2(Ti2−xCrx)O7 with x=0.03, 0.07, and 0.1, and (2) discovering an effective way of installing ferromagnetism in nonmagnetic pyrochlores through Cr doping at the nonmagnetic Ti site. In this Comment, we draw attention to the fact that YCrO3—a well-known antiferromagnetic material with weak ferromagnetic properties—has a Néel temperature (TN) of 140–142 K. The very close match of the magnetic transitions of YCrO3 and Y2(Ti2−xCrx)O7 gives strong evidence that all ferromagnetism in Y2(Ti2−xCrx)O7 originates from the YCrO3 impurity. We prepared simple mixtures of Y2Ti2O7 and YCrO3 compounds containing 0.14 and 0.66 wt. % of YCrO3 and measured the magnetic properties of such mixtures and individual Y2Ti2O7 and YCrO3 compounds. Using the reported magnetic irreversibility values and our experimental values, we estimated the amount of YCrO3 to be below 0.1 wt. % in the original work. It is difficult to detect such levels of impurities with laboratory powder X-ray diffraction. On the other hand, temperature-dependent magnetic measurements at small magnetic fields are much more sensitive to impurities with ferromagneticlike properties.

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    Original Article

    Doping-induced canted ferromagnetism in pyrochlore titanate

    Dipak Sahu, Koushik Pal, Digbijaya Palai, Pradip K. Maji, Debakanta Samal, and Chanchal Sow
    Phys. Rev. B 112, 144412 (2025)

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