- Editors' Suggestion
- Open Access
Cooper condensation and pair wave functions in systems of strongly correlated electrons
Phys. Rev. B 114, 055133 – Published 30 July, 2026
DOI: https://doi.org/10.1103/q1dy-gsmh
Abstract
Identifying superconducting states of matter without prior assumptions is a central challenge in strongly correlated electron systems. We introduce a canonical framework for diagnosing the formation of Cooper pair condensates based on the Penrose–Onsager criterion, in which superconducting order is encoded in the spectral properties of the two-particle reduced density matrix (2RDM). Within this formulation, the symmetry and structure of the condensate are obtained by projecting the 2RDM onto irreducible representations of the underlying symmetry group, enabling an unbiased identification of both conventional and exotic superconducting states. We demonstrate the power and versatility of the approach through applications to the two-dimensional Hubbard model, using both auxiliary-field quantum Monte Carlo (AFQMC) and the density matrix renormalization group (DMRG). For attractive interactions without a magnetic field, we reveal a clear finite-size scaling of the condensate fraction on square lattices of size up to . The framework further provides direct access to the internal structure and extent of Cooper pairs, which we track across the BCS–BEC crossover. Moreover, it enables a clean diagnosis of the finite-momentum Fulde–Ferrell–Larkin–Ovchinnikov (FFLO) phase in a magnetic field. Finally, we apply the approach to a supersolid phase in the repulsive Hubbard model with an additional next-nearest-neighbor hopping , where a charge-density wave coexists with superconductivity. We confirm the fragmented nature of the condensate and uncover substantial pairing correlations in the triplet channel with -wave spatial symmetry in addition to the dominant singlet -wave pairing. Our results establish the 2RDM-based Penrose–Onsager framework as a broadly applicable and unbiased tool for characterizing superconducting order in correlated quantum matter.
Physics Subject Headings (PhySH)
Article Text
References (87)
- C.-C. Chang and S. Zhang, Spin and charge order in the doped Hubbard model: Long-wavelength collective modes, Phys. Rev. Lett. 104, 116402 (2010).
- B.-X. Zheng, C.-M. Chung, P. Corboz, G. Ehlers, M.-P. Qin, R. M. Noack, H. Shi, S. R. White, S. Zhang, and G. K.-L. Chan, Stripe order in the underdoped region of the two-dimensional Hubbard model, Science 358, 1155 (2017).
- E. W. Huang, C. B. Mendl, H.-C. Jiang, B. Moritz, and T. P. Devereaux, Stripe order from the perspective of the Hubbard model, npj Quantum Mater. 3, 22 (2018).
- E. W. Huang, C. B. Mendl, S. Liu, S. Johnston, H.-C. Jiang, B. Moritz, and T. P. Devereaux, Numerical evidence of fluctuating stripes in the normal state of high- cuprate superconductors, Science 358, 1161 (2017).
- M. Qin, C.-M. Chung, H. Shi, E. Vitali, C. Hubig, U. Schollwöck, S. R. White, and S. Zhang (Simons Collaboration on the Many-Electron Problem), Absence of superconductivity in the pure two-dimensional Hubbard model, Phys. Rev. X 10, 031016 (2020).
- H. Xu, H. Shi, E. Vitali, M. Qin, and S. Zhang, Stripes and spin-density waves in the doped two-dimensional Hubbard model: Ground state phase diagram, Phys. Rev. Res. 4, 013239 (2022).
- Y.-F. Jiang, T. P. Devereaux, and H.-C. Jiang, Ground-state phase diagram and superconductivity of the doped Hubbard model on six-leg square cylinders, Phys. Rev. B 109, 085121 (2024).
- H. Xu, C.-M. Chung, M. Qin, U. Schollwöck, S. R. White, and S. Zhang, Coexistence of superconductivity with partially filled stripes in the Hubbard model, Science 384, eadh7691 (2024).
- N. Baldelli, H. Karlsson, B. Kloss, M. Fishman, and A. Wietek, Fragmented superconductivity in the Hubbard model as solitons in Ginzburg–Landau theory, npj Quantum Mater. 10, 22 (2025).
- T. I. Vanhala and P. Törmä, Dynamical mean-field theory study of stripe order and -wave superconductivity in the two-dimensional Hubbard model, Phys. Rev. B 97, 075112 (2018).
- P. Mai, S. Karakuzu, G. Balduzzi, S. Johnston, and T. A. Maier, Intertwined spin, charge, and pair correlations in the two-dimensional Hubbard model in the thermodynamic limit, Proc. Natl. Acad. Sci. USA 119, e2112806119 (2022).
- C. Gros, Superconductivity in correlated wave functions, Phys. Rev. B 38, 931 (1988).
- C. J. Halboth and W. Metzner, -wave superconductivity and Pomeranchuk instability in the two-dimensional Hubbard model, Phys. Rev. Lett. 85, 5162 (2000).
- T. A. Maier, M. Jarrell, T. C. Schulthess, P. R. C. Kent, and J. B. White, Systematic study of -wave superconductivity in the 2D repulsive Hubbard model, Phys. Rev. Lett. 95, 237001 (2005).
- D. Sénéchal, P.-L. Lavertu, M.-A. Marois, and A.-M. S. Tremblay, Competition between antiferromagnetism and superconductivity in high- cuprates, Phys. Rev. Lett. 94, 156404 (2005).
- E. Gull, O. Parcollet, and A. J. Millis, Superconductivity and the pseudogap in the two-dimensional Hubbard model, Phys. Rev. Lett. 110, 216405 (2013).
- Y. Cao, V. Fatemi, S. Fang, K. Watanabe, T. Taniguchi, E. Kaxiras, and P. Jarillo-Herrero, Unconventional superconductivity in magic-angle graphene superlattices, Nature (London) 556, 43 (2018).
- Y. Xia, Z. Han, K. Watanabe, T. Taniguchi, J. Shan, and K. F. Mak, Superconductivity in twisted bilayer , Nature (London) 637, 833 (2025).
- L. Balents, C. R. Dean, D. K. Efetov, and A. F. Young, Superconductivity and strong correlations in moiré flat bands, Nat. Phys. 16, 725 (2020).
- Y. Kamihara, T. Watanabe, M. Hirano, and H. Hosono, Iron-based layered superconductor with , J. Am. Chem. Soc. 130, 3296 (2008).
- Q. Si, R. Yu, and E. Abrahams, High-temperature superconductivity in iron pnictides and chalcogenides, Nat. Rev. Mater. 1, 16017 (2016).
- R. M. Fernandes, A. I. Coldea, H. Ding, I. R. Fisher, P. J. Hirschfeld, and G. Kotliar, Iron pnictides and chalcogenides: A new paradigm for superconductivity, Nature (London) 601, 35 (2022).
- G. Zhou, W. Lv, H. Wang, Z. Nie, Y. Chen, Y. Li, H. Huang, W.-Q Chen, Y.-J. Sun, Q.-K. Xue, and Z. Chen, Ambient-pressure superconductivity onset above in films, Nature (London) 640, 641 (2025).
- F. Li, Z. Xing, D. Peng, J. Dou, N. Guo, L. Ma, Y. Zhang, L. Wang, J. Luo, J. Yang, et al., Bulk superconductivity up to in pressurized nickelate single crystals, Nature (London) 649, 871 (2026).
- D. Li, K. Lee, B. Y. Wang, M. Osada, S. Crossley, H. R. Lee, Y. Cui, Y. Hikita, and H. Y. Hwang, Superconductivity in an infinite-layer nickelate, Nature (London) 572, 624 (2019).
- Y. Wang, K. Jiang, J. Ying, T. Wu, J. Cheng, J. Hu, and X. Chen, Recent progress in nickelate superconductors, Natl. Sci. Rev. 12, nwaf373 (2025).
- Y.-M. Wu, R. Thomale, and S. Raghu, Sublattice interference promotes pair density wave order in kagome metals, Phys. Rev. B 108, L081117 (2023).
- M. S. Hossain, Q. Zhang, E. S. Choi, D. Ratkovski, B. Lüscher, Y. Li, Y.-X. Jiang, M. Litskevich, Z.-J. Cheng, J.-X. Yin, et al., Unconventional gapping behaviour in a kagome superconductor, Nat. Phys. 21, 556 (2025).
- Y. Liu, Z.-Y. Liu, J.-K. Bao, P.-T. Yang, L.-W. Ji, S.-Q. Wu, Q.-X. Shen, J. Luo, J. Yang, J.-Y. Liu, et al., Superconductivity under pressure in a chromium-based kagome metal, Nature (London) 632, 1032 (2024).
- A. Luther and V. J. Emery, Backward scattering in the one-dimensional electron gas, Phys. Rev. Lett. 33, 589 (1974).
- S. Jiang, D. J. Scalapino, and S. R. White, Ground-state phase diagram of the model, Proc. Natl. Acad. Sci. USA 118, e2109978118 (2021).
- S. R. White and D. J. Scalapino, Pairing on striped lattices, Phys. Rev. B 79, 220504(R) (2009).
- J. Venderley and E.-A. Kim, Evidence of pair-density wave in spin-valley locked systems, Sci. Adv. 5, eaat4698 (2019).
- M. Randeria and E. Taylor, Crossover from Bardeen-Cooper-Schrieffer to Bose-Einstein condensation and the unitary Fermi gas, Annu. Rev. Condens. Matter Phys. 5, 209 (2014).
- W. Zwerger, The BCS-BEC Crossover and the Unitary Fermi Gas (Springer, New York, 2011).
- A. J. Leggett, Quantum Liquids: Bose Condensation and Cooper Pairing in Condensed-Matter Systems (Oxford University Press, Oxford, 2006).
- O. Penrose and L. Onsager, Bose-Einstein condensation and liquid helium, Phys. Rev. 104, 576 (1956).
- C. N. Yang, Concept of off-diagonal long-range order and the quantum phases of liquid He and of superconductors, Rev. Mod. Phys. 34, 694 (1962).
- A. Leggett, The Penrose–Onsager–Yang approach to superconductivity and superfluidity, in Dialogues Between Physics and Mathematics: C. N. Yang at 100, edited by M.-L. Ge and Y.-H. He (Springer International Publishing, Cham, 2022), pp. 93–112.
- B. Evrard, A. Qu, J. Dalibard, and F. Gerbier, Observation of fragmentation of a spinor Bose-Einstein condensate, Science 373, 1340 (2021).
- X.-Y. Luo, Y.-Q. Zou, L.-N. Wu, Q. Liu, M.-F. Han, M. K. Tey, and L. You, Deterministic entanglement generation from driving through quantum phase transitions, Science 355, 620 (2017).
- A. Wietek, Fragmented Cooper pair condensation in striped superconductors, Phys. Rev. Lett. 129, 177001 (2022).
- M. Grundner, T. Blatz, J. Sous, U. Schollwöck, and S. Paeckel, Cooper-paired bipolaronic superconductors, arXiv:2308.13427.
- E. H. Lieb, Two theorems on the Hubbard model, Phys. Rev. Lett. 62, 1201 (1989).
- R. T. Scalettar, E. Y. Loh, J. E. Gubernatis, A. Moreo, S. R. White, D. J. Scalapino, R. L. Sugar, and E. Dagotto, Phase diagram of the two-dimensional negative- Hubbard model, Phys. Rev. Lett. 62, 1407 (1989).
- A. Moreo and D. J. Scalapino, Two-dimensional negative- Hubbard model, Phys. Rev. Lett. 66, 946 (1991).
- J. M. Singer, T. Schneider, and M. H. Pedersen, On the phase diagram of the attractive Hubbard model: Crossover and quantum critical phenomena, Eur. Phys. J. B 2, 17 (1998).
- Y. Goto, T. Koma, and H. Yoshida, Superconductivity and low energy excitations in an attractive Hubbard model, arXiv:2509.19780.
- J. Bardeen, L. N. Cooper, and J. R. Schrieffer, Theory of superconductivity, Phys. Rev. 108, 1175 (1957).
- J. R. Waldram, Superconductivity of Metals and Cuprates, 1st ed. (CRC Press, Boca Raton, FL, 1996).
- A. Lüscher, R. M. Noack, and A. M. Läuchli, Fulde-Ferrell-Larkin-Ovchinnikov state in the one-dimensional attractive Hubbard model and its fingerprint in spatial noise correlations, Phys. Rev. A 78, 013637 (2008).
- M. M. Parish, S. K. Baur, E. J. Mueller, and D. A. Huse, Quasi-one-dimensional polarized Fermi superfluids, Phys. Rev. Lett. 99, 250403 (2007).
- S. Cheng, Y. Jiang, Y.-C. Yu, M. T. Batchelor, and X.-W. Guan, Asymptotic correlation functions and FFLO signature for the one-dimensional attractive Hubbard model, Nucl. Phys. B 929, 353 (2018).
- R. Blankenbecler, D. J. Scalapino, and R. L. Sugar, Monte Carlo calculations of coupled boson-fermion systems. I, Phys. Rev. D 24, 2278 (1981).
- H. Shi, P. Rosenberg, S. Chiesa, and S. Zhang, Rashba spin-orbit coupling, strong interactions, and the BCS-BEC crossover in the ground state of the two-dimensional Fermi gas, Phys. Rev. Lett. 117, 040401 (2016).
- P. Rosenberg, H. Shi, and S. Zhang, Ultracold atoms in a square lattice with spin-orbit coupling: Charge order, superfluidity, and topological signatures, Phys. Rev. Lett. 119, 265301 (2017).
- F. F. Assaad, M. Bercx, F. Goth, A. Götz, J. S. Hofmann, E. Huffman, Z. Liu, F. P. Toldin, J. S. E. Portela, and J. Schwab, The ALF (algorithms for lattice fermions) project release 2.0. Documentation for the auxiliary-field quantum Monte Carlo code, SciPost Phys. Codebases 1 (2022).
- J. F. Annett, Superconductivity, Superfluids, and Condensates, 1st ed. (Oxford University Press, Oxford, 2004).
- S. R. White, Density matrix formulation for quantum renormalization groups, Phys. Rev. Lett. 69, 2863 (1992).
- S. R. White, Density-matrix algorithms for quantum renormalization groups, Phys. Rev. B 48, 10345 (1993).
- U. Schollwöck, The density-matrix renormalization group in the age of matrix product states, Ann. Phys. 326, 96 (2011).
- N. D. Mermin and H. Wagner, Absence of ferromagnetism or antiferromagnetism in one- or two-dimensional isotropic Heisenberg models, Phys. Rev. Lett. 17, 1133 (1966).
- P. C. Hohenberg, Existence of long-range order in one and two dimensions, Phys. Rev. 158, 383 (1967).
- M. Fishman, S. R. White, and E. M. Stoudenmire, The ITensor software library for tensor network calculations, SciPost Phys. Codebases 4 (2022).
- M. Fishman, S. R. White, and E. M. Stoudenmire, The ITensor software library for tensor network calculations, SciPost Phys. Codebases 4-r0.3 (2022).
- N. Baldelli, H. Karlsson, and M. Fishman, ITensorCorrelators.jl, 2023, https://github.com/ITensor/ITensorCorrelators.jl.
- Y. Gannot and S. A. Kivelson, How quantum phases on cylinders approach the two-dimensional limit, Phys. Rev. B 107, 075127 (2023).
- H.-C. Jiang, S. A. Kivelson, and D.-H. Lee, Superconducting valence bond fluid in lightly doped eight-leg cylinders, Phys. Rev. B 108, 054505 (2023).
- S. Chatterjee, M. Ippoliti, and M. P. Zaletel, Skyrmion superconductivity: DMRG evidence for a topological route to superconductivity, Phys. Rev. B 106, 035421 (2022).
- P. Fulde and R. A. Ferrell, Superconductivity in a strong spin-exchange field, Phys. Rev. 135, A550 (1964).
- A. I. Larkin and Y. N. Ovchinnikov, Nonuniform state of superconductors, Zh. Eksp. Teor. Fiz. 47, 1136 (1964).
- A. E. Feiguin and F. Heidrich-Meisner, Pairing states of a polarized Fermi gas trapped in a one-dimensional optical lattice, Phys. Rev. B 76, 220508(R) (2007).
- A. Bianchi, R. Movshovich, C. Capan, P. G. Pagliuso, and J. L. Sarrao, Possible Fulde-Ferrell-Larkin-Ovchinnikov superconducting state in , Phys. Rev. Lett. 91, 187004 (2003).
- Y. Matsuda and H. Shimahara, Fulde–Ferrell–Larkin–Ovchinnikov state in heavy fermion superconductors, J. Phys. Soc. Jpn. 76, 051005 (2007).
- H. Shimahara, Theory of the Fulde–Ferrell–Larkin–Ovchinnikov state and application to quasi-low-dimensional organic superconductors, in The Physics of Organic Superconductors and Conductors, edited by A. Lebed (Springer, Berlin, 2008), pp. 687–704.
- S. Imajo, T. Kobayashi, A. Kawamoto, K. Kindo, and Y. Nakazawa, Thermodynamic evidence for the formation of a Fulde-Ferrell-Larkin-Ovchinnikov phase in the organic superconductor , Phys. Rev. B 103, L220501 (2021).
- J. Wosnitza, FFLO states in layered organic superconductors, Ann. Phys. 530, 1700282 (2018).
- R. Casalbuoni and G. Nardulli, Inhomogeneous superconductivity in condensed matter and QCD, Rev. Mod. Phys. 76, 263 (2004).
- A. J. Leggett, Can a solid be “superfluid”? Phys. Rev. Lett. 25, 1543 (1970).
- E. H. da Silva Neto, B. Yu, M. Minola, R. Sutarto, E. Schierle, F. Boschini, M. Zonno, M. Bluschke, J. Higgins, Y. Li, et al., Doping-dependent charge order correlations in electron-doped cuprates, Sci. Adv. 2, e1600782 (2016).
- X. Lu, F. Chen, W. Zhu, D. N. Sheng, and S.-S. Gong, Emergent superconductivity and competing charge orders in hole-doped square-lattice model, Phys. Rev. Lett. 132, 066002 (2024).
- R. S. Mulliken, Report on notation for the spectra of polyatomic molecules, J. Chem. Phys. 23, 1997 (1955).
- R. M. Gray, Toeplitz and circulant matrices: A review, Found. Trends Commun. Inf. Theory 2, 155 (2006).
- P. J. Davis, Circulant Matrices (John Wiley and Sons, New York, 1979).
- G. J. Tee, Eigenvectors of block circulant and alternating circulant matrices, Res. Lett. Inf. Math. Sci. 8, 123 (2005).
- https://alf.physik.uni-wuerzburg.de.
- H. Karlsson, J. S. Hofmann, and A. Wietek, Zenodo, 2026, https://doi.org/10.5281/zenodo.20134789.