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    Disentangling pretransitional fluctuations in metallic VO2

    Javier del Valle1,2,*, Carl Willem Rischau3, Artem Korshunov4, David Ambrosi-Jalón1, Aitana Tarazaga Martín-Luengo1,2, Ibraheem Yousef5, Sara A. Lopez-Paz6, Shany Neyshtadt-Ronel7, Reetendra Singh7 et al.

    Abhishek Rakshit7, Stefano Gariglio3, Alexei Bosak4, and Yoav Kalcheim7

    • *Contact author: javier.delvalle@uniovi.es

    Phys. Rev. B 113, 174114 – Published 18 May, 2026

    DOI: https://doi.org/10.1103/mwd7-pwfm

    Abstract

    VO2 features concomitant structural and metal-insulator transitions. This poses a challenge for understanding the underlying mechanism: Is the transition triggered by a structural or by an electronic instability? The two scenarios are expected to produce very different pretransitional fluctuations above TC. By combining magnetic susceptibility, IR reflectivity, and x-ray diffuse scattering measurements, we observe that metallic VO2 features strong electronic and structural fluctuations toward the insulating monoclinic phase. By measuring resonant diffuse x-ray scattering across the vanadium K edge, we search for a potential decoupling between electronic and structural ordering in these fluctuations, finding no evidence of it. While our results do not completely rule out pure electronic fluctuations, they constrain them, favoring the interpretation that the VO2 metal-insulator transition is triggered by a structural instability. Our work offers a unique approach to solve similar problems in other strongly correlated systems.

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