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Magnetic excitations in the Kitaev material Na2IrO3 studied by neutron scattering

Alexandre Bertin1, Hengdi Zhao2, Gang Cao2, Andrea Piovano3, Paul Steffens3, Alexandre Ivanov3, and Markus Braden1

Phys. Rev. B 113, 094407 – Published 4 March, 2026

DOI: https://doi.org/10.1103/mvn9-nj5n

Abstract

Inelastic neutron scattering experiments with a large set of comounted Na2IrO3 crystals reveal the low-energy magnon dispersion in this candidate material for Kitaev physics. The magnon gap amounts to 1.7(1) meV and can be interpreted similarly to the sister compound α−RuCl3 to stem from the zone boundaries in the antiferromagnetic zigzag structure. The neutron experiments find no evidence for low-energy excitations with ferromagnetic character, which contrasts with the findings in α−RuCl3. Our results are consistent with a recently proposed microscopic model that involves an antiferromagnetic Heisenberg nearest-neighbor exchange in Na2IrO3 in contrast to the ferromagnetic one considered for α−RuCl3. Although the magnetic response shows the signatures of bond-directional anisotropy in both materials the different relative signs of Kitaev and Heisenberg interaction result in different deviations from the initial Kitaev model. Low-energy ferromagnetic fluctuations cannot be considered as a fingerprint of ferromagnetic Kitaev interaction.

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