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    Leading order coefficients in nonlinear thermoelectric responses with time-reversal symmetry

    Ying-Fei Zhang1,*, Zhi-Fan Zhang2,*, Hua Jiang2,3,†, Zhen-Gang Zhu1,4,‡, and Gang Su5,6,§

    • *These authors contributed equally to this work.
    • †Contact author: jianghuaphy@fudan.edu.cn
    • ‡Contact author: zgzhu@ucas.ac.cn
    • §Contact author: gsu@ucas.ac.cn

    Phys. Rev. B 114, 115108 – Published 13 August, 2026

    DOI: https://doi.org/10.1103/ltrw-mntl

    Abstract

    In recent years, nonlinear transport phenomena have garnered significant interest in both theoretical explorations and experiments. In this work, we utilize the semiclassical wave-packet theory to calculate disorder-induced second-order transport coefficients: second-order electrical (σ), thermoelectric (α), and thermal (κ) coefficients, capturing the interplay between side-jump and skew-scattering contributions in systems with time-reversal symmetry. By employing a realistic model of topological insulators specifically tailored to represent Bi2(Se,Te)3 materials, we quantitatively characterize the Fermi-level dependence of these second-order transport coefficients by explicitly including Coulomb impurity potentials. Furthermore, we elucidate the relationships between these coefficients, establishing the second-order Mott relation and the Wiedemann-Franz law induced by disorder. This study develops a comprehensive theoretical framework elucidating the nonlinear thermoelectric transport mechanisms in quantum material systems.

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