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    Static and dynamic properties of the frustrated spin-12 depleted kagome antiferromagnet Cu7(TeO3)2(SO4)2(OH)6

    K. U. Akshay1, Sebin J. Sebastian1,2, Q.-P. Ding2, Y. Furukawa2,3, and R. Nath1,*

    • *Contact author: rnath@iisertvm.ac.in

    Phys. Rev. B 112, 224429 – Published 18 December, 2025

    DOI: https://doi.org/10.1103/l9y5-8646

    Abstract

    The structural and magnetic properties of the two-dimensional spin-1/2 depleted-kagome compound Cu7(TeO3)2(SO4)2(OH)6 are investigated using x-ray diffraction, magnetization, heat capacity, and H1 Nuclear Magnetic Resonance (NMR) measurements. From the analysis of magnetic susceptibility, we found a large Curie-Weiss temperature [θCW=−50(2)K] and the coexistence of antiferromagnetic and ferromagnetic interactions. The value of θCW gives an estimate of the average nearest-neighbor antiferromagnetic interaction of J/kB≃66K. The NMR relaxation rates (1/T1 and 1/T2) exhibit a peak, providing evidence for a magnetic long-range order at T*≃4K which appears to be canted antiferromagnetic type. Heat capacity also features a broad maximum at T* that moves towards higher temperatures with increasing magnetic field, reflecting defect induced Schottky anomaly. The frustration parameter fr=|θCW|/T*≃12.5 renders the compound a highly frustrated low-dimensional magnet.

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