Magnetic and crystal electric field studies of the -based triangular lattice antiferromagnets and
Phys. Rev. B 111, 214437 – Published 24 June, 2025
DOI: https://doi.org/10.1103/ks6z-6nxj
Abstract
We present the low-temperature magnetic properties of two -based triangular lattice compounds, and , studied via thermodynamic measurements followed by crystal electric field (CEF) calculations. Magnetization and specific heat data as well as the CEF energy levels confirm that the ground state is characterized by the low-lying Kramers doublet of the ion with an effective spin- (). A small Curie-Weiss temperature and scaling of magnetic isotherms corroborate very weak magnetic correlations among spins. The crystal field parameters are calculated using the point charge model, and the CEF Hamiltonian is determined for both the compounds. The simulation using the eigenvalues of the CEF Hamiltonian reproduces the experimental magnetic susceptibility, magnetic isotherms, and magnetic specific heat data very well. The large separation between the ground state and first excited state doublets implies that the ground state is a Kramers doublet with at low temperatures, endorsing the experimental findings.