Complex magnetic transitions in the triangular net compound
Phys. Rev. B 113, 144430 – Published 21 April, 2026
DOI: https://doi.org/10.1103/kjct-68sj
Abstract
Thermodynamic and electrical transport properties are reported for single crystals of the trigonal , where complex antiferromagnetic ordering is seen at = 23.3 K and = 20.8 K and a rich phase diagram is revealed under applied magnetic fields. Angle-resolved photoemission spectroscopy (ARPES) measurements provide insights into this behavior by revealing a threefold symmetric Fermi surface that reflects the trigonal space-group symmetry. This promotes competing long-range Ruderman-Kittel-Kasuya-Yosida (RKKY) interactions between localized magnetic moments and is associated with the appearance of fine tuned ordered states. This is accompanied by intrinsic null orbital angular momentum ( 0 for trivalent Gd), which yields Heisenberg spins and ensures that the symmetry of the Fermi surface dominates the magnetic behavior over wide temperature ranges. Comparisons are made to related triangular-net -electron materials, providing guidance for understanding their diverse behaviors.