Understanding the electronic structure of transition-metal dopants in IV–VI semiconductors is critical for tuning their band structure. We analyze properties of the Cr dopant in ${\mathrm{Pb}}_{1-x}{\mathrm{Sn}}_x\mathrm{Te}$ and PbSe by magnetic and transport measurements, which are interpreted based on density functional theory calculations. We demonstrate that the pinning of the Fermi energy to the chromium resonant level occurs for both $n$-type and $p$-type ${\mathrm{Pb}}_{1-\mathrm{x}}{\mathrm{Sn}}_{\mathrm{x}}\mathrm{Te}$ in the whole composition range. This enables us to determine the valence band and conduction band offsets at the PbTe/SnTe/PbSe heterointerfaces, which is important for designing high-performance 2D transistors. Furthermore, the magnetic measurements reveal the presence of Cr ions in three charge states, ${\mathrm{Cr}}^{3+}, {\mathrm{Cr}}^{2+}$, and ${\mathrm{Cr}}^{1+}$. The last one corresponds to the Cr dopants incorporated at the interstitial, and not the substitutional, sites. The measured concentrations of the interstitial and substitutional Cr are comparable.

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• Dopants
• Electrical conductivity
• Magnetism
• Semiconductors
• Density functional calculations