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    Probing magnetic field sensitive criticality in MnP single crystals: From low-field scaling to high-field crossover

    Nguyen Thi My Duc1,2,3,*, Nivarthana W. Y. A. Y. Mudiyanselage4, Shirin Mozaffari5,6, Hasitha Suriya Arachchige5,6, Hari Srikanth4, David Mandrus6, and Manh-Huong Phan1,2,4

    • *Contact author: duc.ntm@vinuni.edu.vn

    Phys. Rev. B 113, 224433 – Published 17 June, 2026

    DOI: https://doi.org/10.1103/jvc4-cwny

    Abstract

    In this study, MnP single crystals were synthesized and comprehensively characterized to elucidate their structural quality, magnetic behavior, magnetocaloric response, and field-dependent critical phenomena along the easy c axis. High-resolution x-ray diffraction confirmed the orthorhombic MnP-type crystal structure with excellent crystallinity. At the same time, magnetization measurements revealed a sharp ferromagnetic transition near room temperature. To further understand the underlying physics governing these behaviors, the critical exponents β, γ, and δ were systematically extracted in three distinct magnetic-field regimes, low, medium, and high, thus enabling a detailed assessment of universality and crossover effects in this anisotropic itinerant ferromagnet. In the low-field regime, we obtained a Curie temperature TC=288.69±10.01K, with critical exponents β=0.355±0.016, γ=1.208±0.021, and δ=4.407±0.167. For medium fields, the transition sharpened and shifted toward higher temperature, yielding TC=294.52±4.08K, β=0.368±0.022, γ=0.995±0.010, and δ=3.701±0.031. In the high-field regime, the system displayed a pronounced crossover from nearly second-order to more mean-field-like behavior, with TC=300.26±2.00K, β=0.490±0.049, γ=1.058±0.035, and δ=3.158±0.227. These systematic variations indicate strong field sensitivity of the magnetic interactions and highlight a continuous evolution of the critical behavior across the three regimes. The intrinsic thermodynamic TC is approximately 296 K, while the field-dependent values extracted from modified Arrott plot/Kouvel-Fisher analyses represent effective crossover temperatures. This work provides a unified picture of the structural, magnetic, magnetocaloric, and critical properties of MnP single crystals. The field-dependent critical exponents demonstrate that MnP exhibits nonuniversal scaling governed by magnetic anisotropy and external-field strength, offering valuable insight into both fundamental studies of criticality and the optimization of MnP-based magnetocaloric materials near room temperature.

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