Probing magnetic field sensitive criticality in MnP single crystals: From low-field scaling to high-field crossover
Phys. Rev. B 113, 224433 – Published 17 June, 2026
DOI: https://doi.org/10.1103/jvc4-cwny
Abstract
In this study, MnP single crystals were synthesized and comprehensively characterized to elucidate their structural quality, magnetic behavior, magnetocaloric response, and field-dependent critical phenomena along the easy axis. High-resolution x-ray diffraction confirmed the orthorhombic MnP-type crystal structure with excellent crystallinity. At the same time, magnetization measurements revealed a sharp ferromagnetic transition near room temperature. To further understand the underlying physics governing these behaviors, the critical exponents β, γ, and δ were systematically extracted in three distinct magnetic-field regimes, low, medium, and high, thus enabling a detailed assessment of universality and crossover effects in this anisotropic itinerant ferromagnet. In the low-field regime, we obtained a Curie temperature , with critical exponents , and . For medium fields, the transition sharpened and shifted toward higher temperature, yielding , and . In the high-field regime, the system displayed a pronounced crossover from nearly second-order to more mean-field-like behavior, with , and . These systematic variations indicate strong field sensitivity of the magnetic interactions and highlight a continuous evolution of the critical behavior across the three regimes. The intrinsic thermodynamic is approximately 296 K, while the field-dependent values extracted from modified Arrott plot/Kouvel-Fisher analyses represent effective crossover temperatures. This work provides a unified picture of the structural, magnetic, magnetocaloric, and critical properties of MnP single crystals. The field-dependent critical exponents demonstrate that MnP exhibits nonuniversal scaling governed by magnetic anisotropy and external-field strength, offering valuable insight into both fundamental studies of criticality and the optimization of MnP-based magnetocaloric materials near room temperature.