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    High-field crossover from linear to nonlinear magnetoelectric effect in Co3O4

    S. Ghara1,*, Y. Kinoshita2, A. Miyake3, Y. Ishii2, L. Prodan1, V. Tsurkan1,4, Y. Skourski5, J. Wosnitza5,6, Y. H. Matsuda2 et al.

    S. Miyahara7, M. Tokunaga2, and I. Kézsmárki1

    • *Contact author: somnath.ghara@physik.uni-augsburg.de

    Phys. Rev. B 114, 024417 – Published 20 July, 2026

    DOI: https://doi.org/10.1103/j66k-pc7d

    Abstract

    The A-site magnetic spinel Co3O4 exhibits a simple Néel-type collinear antiferromagnetic ordering below TN=30 K, accompanied by a strong linear magnetoelectric effect. Here, we report magnetization and electric polarization measurements on single crystals of Co3O4 up to high magnetic fields. We show that the magnetoelectric polarization undergoes a crossover from linear to nonlinear behavior with increasing magnetic field, followed by complete suppression upon reaching the field-polarized ferromagnetic state, where inversion symmetry is recovered. Our microscopic spin model, reproducing the observed field evolution of the magnetoelectric response, evidences weak anisotropy that is crucial for the effective magnetoelectric control of the antiferromagnetic state [Phys. Rev. Lett. 135, 126704 (2025)].

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