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    Enhancement of the superconducting transition temperature due to multiband effect in the topological nodal-line semimetal Pb1−xSnxTaSe2

    K. Kumarasinghe1, A. Rahman1, M. Tomlinson1, D. Le1, F. Joshua2,3, L. Zhai2,3, and Y. Nakajima1,*

    • *Contact author: Yasuyuki.Nakajima@ucf.edu

    Phys. Rev. B 112, 054504 – Published 6 August, 2025

    DOI: https://doi.org/10.1103/hsdq-2tp9

    Abstract

    We report a systematic study of the normal-state and superconducting properties of single-crystal Pb1−xSnxTaSe2 (0≤x≤0.23). Sn doping enhances the superconducting temperature Tc up to 5.1 K while also significantly increasing impurity scattering in the crystals. For x=0 and 0.018, the specific-heat jump at Tc exceeds the Bardeen-Cooper-Schrieffer (BCS) weak-coupling value of 1.43, indicating the realization of strong-coupling superconductivity in undoped and slightly-Sn-doped PbTaSe2. Substituting Pb with more Sn lowers the specific-heat jump at Tc below the BCS value of 1.43, which cannot be explained by a single-gap model. Rather, the observed specific-heat data of moderately-Sn-doped PbTaSe2 (x=0.08 and 0.15) are reproduced by a two-gap model. Our density functional theory calculations suggest that three-dimensional Fermi pockets appear due to a reduction of the spin-orbit gap with Sn doping, and the multiband effect arising from these emergent Fermi pockets enhances the effective electron-phonon coupling strength, leading to the increase in Tc of Pb1−xSnxTaSe2.

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