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    Anomalous electrical transport in SnSe2 nanosheets: Role of thickness and surface defect states

    Aarti Lakhara1, Lars Thole2, Rolf J. Haug2,*, and P. A. Bhobe1,†

    • *Contact author: haug@nano.uni-hannover.de
    • †Contact author: pbhobe@iiti.ac.in

    Phys. Rev. B 112, 235401 – Published 1 December, 2025

    DOI: https://doi.org/10.1103/hrp5-pts7

    Abstract

    This work examines the influence of thickness on the electrical transport properties of mechanically exfoliated two-dimensional SnSe2 nanosheets, derived from the bulk single crystal. Contrary to the conventional trend observed in two-dimensional systems, we find a semiconducting to metallic resistivity behavior with decreasing thickness. The analysis of low-temperature conduction indicates an increased density of states at the Fermi level with decreasing thickness, which is further corroborated by gate bias-dependent conductance measurement. The enhanced conductivity in thinner flake is attributed to the n-type doping arising from surface defect states. The presence and evolution of these defect states with thickness are probed by thickness-dependent room-temperature Raman spectroscopy. Our study provides insights into the thickness-dependent electronic transport mechanism of SnSe2 and the crucial role of defect states in governing the observed conductivity behavior.

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