Anomalous electrical transport in nanosheets: Role of thickness and surface defect states
Phys. Rev. B 112, 235401 – Published 1 December, 2025
DOI: https://doi.org/10.1103/hrp5-pts7
Abstract
This work examines the influence of thickness on the electrical transport properties of mechanically exfoliated two-dimensional nanosheets, derived from the bulk single crystal. Contrary to the conventional trend observed in two-dimensional systems, we find a semiconducting to metallic resistivity behavior with decreasing thickness. The analysis of low-temperature conduction indicates an increased density of states at the Fermi level with decreasing thickness, which is further corroborated by gate bias-dependent conductance measurement. The enhanced conductivity in thinner flake is attributed to the -type doping arising from surface defect states. The presence and evolution of these defect states with thickness are probed by thickness-dependent room-temperature Raman spectroscopy. Our study provides insights into the thickness-dependent electronic transport mechanism of and the crucial role of defect states in governing the observed conductivity behavior.