Multiple-gap weak-coupling superconductivity in the full-Heusler compound
Phys. Rev. B 113, 184510 – Published 7 May, 2026
DOI: https://doi.org/10.1103/h91m-wh75
Abstract
Superconductivity was observed in the full-Heusler compound below 1.4 K. Polycrystalline samples of were prepared by the arc-melting method. adopts a centrosymmetric cubic structure with the space group Fm-. Electrical-resistivity and magnetic-susceptibility measurements reveal that is a type-II superconductor with a large Ginzburg-Landau parameter. The upper critical field of T is slightly lower than the Bardeen-Cooper-Schrieffer Pauli limit ( T) in this three-dimensional superconductor with inversion symmetry, suggesting conventional superconducting states. Thermodynamic and transport data evidence the multigap weak-coupling BCS regime of . In addition, we note that a charge density wave like transition lies at K. First-principles calculations indicate that the Pd- and Ti- orbits dominate the states at the Fermi level (), showing that different electronic components induce the multiband characters. The flat band topology and van Hove singularity near contribute to the superconducting and charge instabilities in this system. The discovery of the first Ti-containing Heusler superconductor may benefit to make sense of the pairing mechanisms of Heusler-phase and other related intermetallic superconductors.