Strongly quenched Kramers doublet magnetism in
Phys. Rev. B 113, 224443 – Published 24 June, 2026
DOI: https://doi.org/10.1103/gt2r-3mn7
Abstract
We report magnetic susceptibility, isothermal magnetization, and specific-heat measurements on the rare-earth hexaaluminate , where realizes a strongly quenched Kramers doublet on a triangular lattice with an exceptionally weak net exchange scale. Curie-Weiss analysis yields strongly reduced ground-doublet factors, and , indicating that the low-temperature response is governed primarily by single-ion physics, with crystal-field splitting and -multiplet mixing renormalizing the moment rather than collective exchange. For , the specific heat shows no -type anomaly down to 0.35 K, but evolves in field into a two-level Schottky peak whose gap increases linearly with field. The Schottky analysis yields and recovers nearly all of at high fields, supporting an effective Kramers doublet description for . Overall, the data place in an extreme weak-exchange, single-ion–dominated regime, with low-temperature deviations from ideal two-level behavior that may reflect a combination of geometric frustration, multiplet mixing, and structural disorder, while no long-range order is observed within our experimental window.