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    Strongly quenched Kramers doublet magnetism in SmMgAl11O19

    Sonu Kumar1,2,*, Barbora Salajová1, Andrej Kancko1, Cinthia A. Corrêa3, Shuvajit Halder1, and Ross H. Colman1,†

    • *Contact author: sonu.kumar@matfyz.cuni.cz
    • †Contact author: ross.colman@matfyz.cuni.cz

    Phys. Rev. B 113, 224443 – Published 24 June, 2026

    DOI: https://doi.org/10.1103/gt2r-3mn7

    Abstract

    We report magnetic susceptibility, isothermal magnetization, and specific-heat measurements on the rare-earth hexaaluminate SmMgAl11O19, where Sm3+ realizes a strongly quenched Kramers doublet on a triangular lattice with an exceptionally weak net exchange scale. Curie-Weiss analysis yields strongly reduced ground-doublet g factors, gab≃0.65 and gc≃0.70, indicating that the low-temperature response is governed primarily by single-ion physics, with crystal-field splitting and J-multiplet mixing renormalizing the Sm3+ moment rather than collective exchange. For H∥c, the specific heat shows no λ-type anomaly down to 0.35 K, but evolves in field into a two-level Schottky peak whose gap increases linearly with field. The Schottky analysis yields gc≃0.62 and recovers nearly all of Rln2 at high fields, supporting an effective Seff=12 Kramers doublet description for T≲10K. Overall, the data place SmMgAl11O19 in an extreme weak-exchange, single-ion–dominated regime, with low-temperature deviations from ideal two-level behavior that may reflect a combination of geometric frustration, multiplet mixing, and structural disorder, while no long-range order is observed within our experimental window.

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