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    Magnetism and nontrivial topological phases in the kagome materials M3X2S2(M=Rh,Ni;X=Sn,Pb)

    Danwen Yuan1,2, Shuai Zhang3,*, Jia Chen4,5, Hongming Weng6,7, and Wei Zhang1,2,†

    • *Contact author: zhangshuai@itp.ac.cn
    • †Contact author: zhangw721@163.com

    Phys. Rev. B 112, 085122 – Published 13 August, 2025

    DOI: https://doi.org/10.1103/f79k-t2tz

    Abstract

    The kagome materials with tunable magnetism and nontrivial topological state are appealing in both the theoretical study and the applications, such as the spintronics device and topological quantum calculations. In this work, we study the magnetism and topological states of the shandite kagome materials family M3X2S2(M=Rh,Ni;X=Sn,Pb) comprehensively. Under the nonmagnetic states, Rh3Sn2S2 is a strong topological insulator after doping one electron in the primitive cell and Rh3Pb2S2 is the Dirac semimetal. Rh3Sn2S2 has flat bands and a sharp density of state peak near the Fermi level, which induces itinerant ferromagnetism. In the ferromagnetic state, Rh3Sn2S2 shows a Weyl semimetal phase and an axion insulator phase under different occupations. Due to the different hybridization between d orbitals of Rh and s orbitals of Sn/Pb, the isomorphic material Rh3Pb2S2 has no magnetic order, which is different from that of Rh3Sn2S2. Meanwhile, Ni3Pb2S2 has three more electrons in the primitive cell and no magnetization in our calculations. It shows a weak topological insulator state. Our work reveals the magnetism and nontrivial topological phases in the shandite kagome materials family M3X2S2(M=Rh,Ni;X=Sn,Pb). The tunable magnetism and topological states also provide a material platform for the further study of novel physical phenomena related to the magnetic nontrivial topological properties and further applications.

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