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    Nonsymmorphic symmetry protected hourglass Dirac chain topology and conventional superconductivity in ZrIrGe

    Pavan Kumar Meena1,*, Dibyendu Samanta2,*, Shashank Srivastava1, Poulami Manna1, Sudeep Kumar Ghosh2,†, and Ravi Prakash Singh1,‡

    • *These authors contributed equally to this work.
    • †Contact author: skghosh@iitk.ac.in
    • ‡Contact author: rpsingh@iiserb.ac.in

    Phys. Rev. B 112, 144515 – Published 17 October, 2025

    DOI: https://doi.org/10.1103/dch7-3f7y

    Abstract

    Ternary transition-metal germanide superconductors with nonsymmorphic symmetries offer promising platforms for symmetry-protected topological phases. In this work, we investigate ZrIrGe, which crystallizes in the nonsymmorphic TiNiSi-type structure. Electrical, magnetic, and specific heat measurements confirm bulk type-II superconductivity with a full gap and a transition temperature of 2.84(7) K, consistent with weak-coupling BCS behavior. First-principles calculations reveal hourglass-shaped bulk band dispersions and a Dirac chain composed of symmetry-protected fourfold-degenerate Dirac points, leading to drumheadlike surface states near the Fermi level. Additionally, ZrIrGe exhibits a nontrivial Z2 topological character, resulting in helical surface states that cross the Fermi level, making it a strong candidate for proximity-induced topological superconductivity. The coexistence of conventional superconductivity and topological band features establishes ZrIrGe as a rare stoichiometric system for exploring intrinsic topological superconductivity.

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