We demonstrate the existence of an unconventional pairing state in photodoped Mott insulators on ladder and quasi-two-dimensional geometries, characterized by quasi-long-range doublon-holon correlations that signal Mott exciton condensation. The doublon-holon pairing exhibits correlations of $d$-wave-like symmetry, reminiscent of superconducting pairing in chemically doped Mott insulators. By constructing the phase diagram, using density matrix renormalization group, we reveal that the doublon-holon pairing state in the photodoped ladder emerges between the spin-singlet, charge-density-wave, and $\eta$-pairing phases. Our study suggests that the interplay of charge, spin, and $\eta$-spin degrees of freedom can give rise to exotic quantum many-body states in photodoped Mott insulators.

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• Pairing mechanisms
• Photoinduced effect
• Mott insulators
• Quantum many-body systems
• Strongly correlated systems
• Density matrix renormalization group
• Hubbard model