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    Absorbance marker: Detection of quantum geometry and spread of Wannier function in disordered two-dimensional semiconductors

    Luis F. Cárdenas-Castillo, Shuai Zhang*, Fernando L. Freire, Jr., and Wei Chen†

    • Department of Physics, PUC-Rio, 22451-900 Rio de Janeiro, Brazil

    • *Contact author: zhangshuai0018@outlook.com
    • †Contact author: wchen@puc-rio.br

    Phys. Rev. B 112, 085402 – Published 1 August, 2025

    DOI: https://doi.org/10.1103/ch8q-p7f7

    Abstract

    The optical absorbance of two-dimensional semiconductors is generalized to individual lattice sites through the topological marker formalism, yielding an absorbance marker. This marker allows us to investigate the atomic-scale variation of absorbance caused by impurities and thereby quantify the influence of disorder on the quantum geometry and the spread of Wannier functions of valence-band states. Applying this marker to transition-metal dichalcogenides reveals a very localized suppression of absorbance caused by potential impurities, rendering a reduction of absorbance in the macroscopic scale proportional to the impurity density, in good agreement with the experimental results of plasma-treated WS2.

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