Export citation

Export citation

Choose format for download:

Download Citation
  • Letter

Generalized many-body exciton g factors: Magnetic hybridization and nonmonotonic Rydberg series in monolayer WSe2

Paulo E. Faria Junior1,2,3,*,†, Daniel Hernangómez-Pérez4,*,‡, Tomer Amit5,*, Jaroslav Fabian3, and Sivan Refaely-Abramson5

  • *These authors contributed equally to this work.
  • †Contact author: paulo@ucf.edu
  • ‡Contact author: d.hernangomez@nanogune.eu

Phys. Rev. B 112, L241404 – Published 3 December, 2025

DOI: https://doi.org/10.1103/c5y7-w9tk

Abstract

The magneto-optical response of excitons in monolayer transition metal dichalcogenides is governed by a complex interplay of Bloch-state quantum geometry—reflected in the electronic magnetic moment—coupled with interband mixing and many-body interactions. Here, we develop a robust and general first-principles framework for many-body exciton g factors (magnetic moments) by incorporating off-diagonal terms for the spin and orbital angular momenta of single-particle bands and many-body states for magnetic fields pointing in arbitrary spatial directions. We implement our framework using many-body perturbation theory via the GW-Bethe-Salpeter equation  and supplement our analysis with robust symmetry-based models. Focusing on the archetypal monolayer WSe2, we accurately reproduce the known results of the low-energy excitons including the Zeeman splitting and the dark/gray exciton brightening. Furthermore, our theory naturally reveals the magnetic-field hybridization of higher-energy excitons (s, p, and d like) and shows that the magnetic moments of nodal excitons (p and d like) do not acquire additional contributions of ±mjμB (mj=1,2), characteristic of the hydrogenic picture. Our general approach also allows us to resolve the long-standing puzzle of the experimentally measured nonmonotonic Rydberg series (1s−4s) of exciton g factors. Our framework offers a comprehensive approach to investigate, rationalize, and predict the nontrivial interplay between magnetic fields, angular momenta, and many-body exciton physics in van der Waals systems, offering different opportunities to probe signatures of quantum geometry within many-body states.

Physics Subject Headings (PhySH)

Authorization Required

We need you to provide your credentials before accessing this content.

Supplemental Material (Subscription Required)

References (Subscription Required)

Outline

Information

Sign In to Your Journals Account

Filter

Filter

Article Lookup

Enter a citation