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Iron displacements and magnetoelastic coupling in the antiferromagnetic spin-ladder compound BaFe2Se3

J. M. Caron1, J. R. Neilson1, D. C. Miller1, A. Llobet2, and T. M. McQueen1,*

  • 1Institute for Quantum Matter, Department of Chemistry, and Department of Physics and Astronomy, The Johns Hopkins University, Baltimore, Maryland 21030, USA
  • 2Lujan Neutron Scattering Center, Los Alamos National Laboratory, Los Alamos, New Mexico 87545, USA

  • *mcqueen@jhu.edu

Phys. Rev. B 84, 180409(R) – Published 16 November, 2011

DOI: https://doi.org/10.1103/PhysRevB.84.180409

Abstract

We report long-range-ordered antiferromagnetism concomitant with local iron displacements in the spin-ladder compound BaFe2Se3. Short-range magnetic correlations, present at room temperature, develop into long-range antiferromagnetic order below TN = 256 K, with no superconductivity down to 1.8 K. Built of ferromagnetic Fe4 plaquettes, the magnetic ground state correlates with local displacements of the Fe atoms. These iron displacements imply significant magnetoelastic coupling in FeX4-based materials, ingredients hypothesized to be important in the emergence of superconductivity. This result also suggests that knowledge of these local displacements is essential for properly understanding the electronic structure of these systems. As with the copper oxide superconductors two decades ago, our results highlight the importance of reduced dimensionality spin-ladder compounds in the study of the coupling of spin, charge, and atom positions in superconducting materials.

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