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    Evidence for a strain-stabilized bct phase of cobalt deposited on Pd{100}: An x-ray photoelectron diffraction study

    Hélène Giordano, Andrea Atrei, Marco Torrini, and Ugo Bardi

    Michael Gleeson and Colin Barnes

    • Dipartimento di Chimica, Università di Firenze, Via G. Capponi 9, 50121 Firenze, Italy

    • Dublin City University, School of Chemical Sciences, Dublin 9, Ireland

    Phys. Rev. B 54, 11762 – Published 15 October, 1996

    DOI: https://doi.org/10.1103/PhysRevB.54.11762

    Abstract

    The structure of cobalt layers grown on a Pd{100} single-crystal surface has been studied by scanned angle x-ray photoelectron diffraction. At room temperature the cobalt layers grow in a structure related to the bulk cobalt fcc phase characterized by a large expansion of the in-plane lattice parameters and a corresponding contraction of the interlayer spacing (∼10%). This structure persists to coverages greater than 30-layer equivalents, and can be interpreted as a metastable body-centered-tetragonal (bct) phase. © 1996 The American Physical Society.

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