Magnetic Circular Dichroism of Impurities in Solids: Vibrationally Induced Transitions in MgO: Ni
Phys. Rev. B 5, 1800 – Published 1 March, 1972
DOI: https://doi.org/10.1103/PhysRevB.5.1800
Abstract
We report absorption spectra and magnetic circular dichroism (MCD) of transitions in single-crystal MgO:Ni over the range 4-300°K. General theoretical expressions for the zeroth and first moments of the absorption and MCD of a vibration-induced band are derived. Their application to the MgO: Ni data leads to the conclusion that the intensities of the , , and bands are predominantly induced via vibrations. A consistent qualitative analysis of observed structure in these bands is made. The main vibrational structure is assigned to the dispersion of the allowing phonons. All spin-orbit components of the band are identified. The analysis does not require Jahn-Teller effects to be invoked in any of these bands.