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    Magnetic Circular Dichroism of Impurities in Solids: Vibrationally Induced d→d Transitions in MgO: Ni

    B. D. Bird, G. A. Osborne, and P. J. Stephens*

    • Department of Chemistry, University of Southern California, Los Angeles, California 90007

    • *Alfred P. Sloan Foundation Fellow.

    Phys. Rev. B 5, 1800 – Published 1 March, 1972

    DOI: https://doi.org/10.1103/PhysRevB.5.1800

    Abstract

    We report absorption spectra and magnetic circular dichroism (MCD) of d→d transitions in single-crystal MgO:Ni over the range 4-300°K. General theoretical expressions for the zeroth and first moments of the absorption and MCD of a vibration-induced band are derived. Their application to the MgO: Ni data leads to the conclusion that the intensities of the T1a3, T21, and T1b3 bands are predominantly induced via t1u vibrations. A consistent qualitative analysis of observed structure in these bands is made. The main vibrational structure is assigned to the dispersion of the allowing t1u phonons. All spin-orbit components of the T1a3 band are identified. The analysis does not require Jahn-Teller effects to be invoked in any of these bands.

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