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Particle-size effects on the value of Tc of MnFe2O4: Evidence for finite-size scaling

G. U. Kulkarni, K. R. Kannan, T. Arunarkavalli, and C. N. R. Rao

  • Council for Scientific and Industrial Research Centre of Excellence in Chemistry and Solid State and Structural Chemistry Unit, Indian Institute of Science, Bangalore 560 012, India

Phys. Rev. B 49, 724(R) – Published 1 January, 1994

DOI: https://doi.org/10.1103/PhysRevB.49.724

Abstract

Fe57 Mössbauer measurements show that the Tc of 〈12〉-nm particles of MnFe2O4 is higher than that of the 〈33〉-nm particles, which exhibit the bulk Tc value (573 K). The Fe57 isomer shift as well as the internal field are, however, independent of the particle size, as is the cation distribution determined by Mn and Fe extended x-ray absorption fine structure and Mn x-ray absorption near-edge structure measurements at different temperatures. The results confirm that the higher Tc of the 〈12〉-nm particles arises from finite-size scaling.

Comments & Replies

Comment on ‘‘Particle-size effects on the value of TC of MnFe2O4: Evidence for finite-size scaling’’

P. J. van der Zaag, V. A. M. Brabers, M. T. Johnson, A. Noordermeer, and P. F. Bongers
Phys. Rev. B 51, 12009 (1995)

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