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Particle-size effects on the value of of : Evidence for finite-size scaling
Phys. Rev. B 49, 724(R) – Published 1 January, 1994
DOI: https://doi.org/10.1103/PhysRevB.49.724
Abstract
Mössbauer measurements show that the of 〈12〉-nm particles of is higher than that of the 〈33〉-nm particles, which exhibit the bulk value (573 K). The isomer shift as well as the internal field are, however, independent of the particle size, as is the cation distribution determined by Mn and Fe extended x-ray absorption fine structure and Mn x-ray absorption near-edge structure measurements at different temperatures. The results confirm that the higher of the 〈12〉-nm particles arises from finite-size scaling.
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Phys. Rev. B 51, 12009 (1995)