Hydrogenation of thin Y-Ba-Cu-O films: Electrical transport and structure properties of and
Phys. Rev. B 49, 600 – Published 1 January, 1994
DOI: https://doi.org/10.1103/PhysRevB.49.600
Abstract
c-axis-oriented (1:2:3) and (1:2:4) thin films were charged with hydrogen at 463 K and a pressure of 100 mbar. The hydrogen concentrations and depth profiles were measured with the nuclear reaction method. In contrast to earlier studies on bulk samples where a constant is reported, we find in our 1:2:3 films that the superconducting transition temperature decreases continuously with increasing hydrogen concentration and that the transitions remain relatively sharp, e.g., =38 K and Δ=6.2 K for [H]/cell≃0.6. The electrical resistivity and Hall-effect measurements in the normal state indicate that the main effect of hydrogen doping is a reduction of the charge carrier concentration, whereas the carrier mobility is not changed significantly. At an average hydrogen concentration of [H]/cell≃2 in both systems, a new hydride phase is observed, which for 1:2:3 is characterized by a c-axis expansion of 16% and for 1:2:4 by a c-axis expansion of 1.5%.