Tiling-decoration model of the quasicrystal i-
Phys. Rev. B 49, 100 – Published 1 January, 1994
DOI: https://doi.org/10.1103/PhysRevB.49.100
Abstract
We propose a tiling-and-decoration model of the icosahedral phase of Al-Mn-Si, in which a 126-atom ‘‘double’’ Mackay icosahedron and a 54-atom ‘‘simple’’ Mackay icosahedron alternate on the even and odd nodes of the tiling of four canonical cells. The model structure exhibits weak six-dimensional fcc ordering introduced by Al-vacancy alternation, similar to that observed in the related α phase. The density of the model is consistent with experimental data and calculation of the x-ray- and neutron-diffraction intensities leads to good agreement with experimental data in both cases: R factors are 0.09 and 0.16, respectively.