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    Exciton-polariton luminescence from sodium cryptand sodide [Na+(C222)Na−]

    Ta-Ryeong Park

    Stuart A. Solin

    James L. Dye

    • Department of Physics and Astronomy and Center for Fundamental Materials Research, Michigan State University, East Lansing, Michigan 48824

    • NEC Research Institute, Princeton, New Jersey 08540

    • Department of Chemistry and Center for Fundamental Materials Research, Michigan State University, East Lansing, Michigan 48824

    Phys. Rev. B 46, 817 – Published 1 July, 1992

    DOI: https://doi.org/10.1103/PhysRevB.46.817

    Abstract

    We have performed spatially and temporally resolved luminescence experiments on various-sized crystals of sodium cryptand [2.2.2] sodide to observe directly the spatial propagation of the optically excited state as well as the dependence of the luminescence specta on crystal size. Small crystals (≤≊50 μm) exhibit a line shape that is distinct from that of larger crystals. A formalism based on polariton dynamics is developed to explain the time-evolution behavior and the dependence of the luminescence on crystal size.

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