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    Cubic magnetic anisotropy of nonstoichiometric magnetite

    Ricardo Aragón

    • Department of Chemical Engineering, University of Delaware, Newark, Delaware 19716

    Phys. Rev. B 46, 5334 – Published 1 September, 1992

    DOI: https://doi.org/10.1103/PhysRevB.46.5334

    Abstract

    The cubic magnetic anisotropy constants of Fe3(1−δ)O4 single crystals (with 0.000<δ<0.006), obtained by curve fitting of the respective magnetization curves, are reported between room temperature and the isotropic point (∼130 K), where the easy axis changes from [111] to [100]. Two distinct temperature dependences are observed for nonstoichiometries above and below δC=0.0039, in samples with second- and first-order Verwey transitions, respectively. The characteristic temperatures for the first-derivative curves are consistent with mean-field parameters for nearest-neighbor-interaction models.

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