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    One-dimensional vibrations and disorder: The Zr1−xHfxS3 solid solution

    A. Ait-Ouali, S. Jandl, and P. Marinier

    J.-M. Lopez-Castillo

    A.-M. S. Tremblay

    • Département de Physique and Centre de Recherche en Physique du Solide, Université de Sherbrooke, Sherbrooke, Québec, Canada J1K 2R1

    • Département de Médecine Nucléaire et de Radiobiologie, Faculté de Médecine, Université de Sherbrooke, Sherbrooke, Québec, Canada J1H 5N4

    • Département de Physique and Centre de Recherche en Physique du Solide, Université de Sherbrooke, Sherbrooke, Québec, Canada J1K 2R1

    Phys. Rev. B 46, 5183 – Published 1 September, 1992

    DOI: https://doi.org/10.1103/PhysRevB.46.5183

    Abstract

    In the trichalcogenide family of compounds Zr1−xHfxS3 there is a frequency range where the optic modes are expected to be describable by a simple one-dimensional model. It is shown that the disorder-induced linewidth in the relevant frequency range could be consistent with theoretical calculations for a simple diatomic chain model. The vibrations involved are along the chain direction and are of Bg type. All the Bg modes of this family of compounds are also here unequivocally identified.

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