Magnetic ordering and chain transport of
Phys. Rev. B 46, 1176 – Published 1 July, 1992
DOI: https://doi.org/10.1103/PhysRevB.46.1176
Abstract
The effects of Fe, Co, and Ni substitution on the structural, magnetic, and electrical properties of have been investigated by means of powder x-ray diffraction, magnetization, and electrical-resistivity measurements. All three systems ( (M=Fe, Co, and Ni) exhibit an orthorhombic-tetragonal transition at about x=0.025 for Fe and Co, and x=0.05 for Ni. The magnetic ordering temperature of is reduced by the doping of Fe, Co, and Ni with the depression rate /dx∼0.65, 0.75, and 0.45 K/at. %, respectively. The doping of Fe or Co has a larger effect than Ni on the increase of room-temperature resistivity. Combining these results with those observed previously in Zn- and Ga-doped , it is interpreted that the Cu-O chain is considered to play a crucial role in the magnetic-coupling mechanism of .