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    Site Occupancy of the PbWO4:Co and PbMoO4:Co Systems

    M. -C. Chen*

    J. O. Artman and D. Sengupta

    J. C. M. Henning

    • College of Engineering, National Chiao Tung University, Hsinchu, Taiwan, China

    • Department of Physics and Electrical Engineering, Carnegie-Mellon University, Pittsburgh, Pennsylvania 15213

    • Philips Research Laboratories, N. V. Philips 'Gloeilampenfabrieken, Eindhoven, The Netherlands

    • *On leave from Research Laboratories, General Motors Corporation, Warren, Mich. 48090.

    Phys. Rev. B 4, 1387 – Published 15 August, 1971

    DOI: https://doi.org/10.1103/PhysRevB.4.1387

    Abstract

    In a previous investigation of Co-doped PbWO4 and PbMoO4, the EPR data were attributed to Co2+ ions occupying tetrahedral W (or Mo) sites of S4 symmetry. Several years ago, Blasse proposed that the interstitial octahedral sites in scheelites could be occupied by U6+ ions. After reexamination of the g value and hyperfine-structure (hfs) data and from the 2D estimates, the case for interstitial site occupancy by Co2+ in these two scheelites can be made plausible. Although they are not conclusive, the optical data are compatible with this assignment.

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