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  • Letter

Multipolar multiferroics in 4d2/5d2 Mott insulators

Saikat Banerjee1,2,*, Stephan Humeniuk2, Alan R. Bishop1, Avadh Saxena1, and Alexander V. Balatsky3,4

  • *Contact author: saikat.banerjee@rutgers.edu

Phys. Rev. B 111, L201107 – Published 12 May, 2025

DOI: https://doi.org/10.1103/PhysRevB.111.L201107

Abstract

We extend the concept of conventional multiferroicity—where ferroelectric and ferromagnetic orders coexist—to include multipolar degrees of freedom. Specifically, we explore how this phenomenon emerges in 4d2/5d2 Mott insulators with strong spin-orbit and Hund's couplings. Our study uncovers the origin of magnetic multipolar interactions in these systems and demonstrates that a combination of quadrupolar and octupolar magnetic order can simultaneously induce both electrical quadrupolar moments and ferroelectric polarization. By expanding the multiferroic framework to higher-order multipoles, we reveal the possibility of coexisting multipolar orders of different or same ranks, paving the way for different functional properties in a large class of strongly correlated materials.

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