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  • Letter

(H,Li)6Ru2O6: A possible zero-field Ru3+-based Kitaev quantum spin liquid

Sanjay Bachhar1,*, M. Baenitz2, Hubertus Luetkens3, John Wilkinson4, Sumiran Pujari1, and A. V. Mahajan1,†

  • *Contact author: sanjayphysics95@gmail.com
  • †Contact author: mahajan@phy.iitb.ac.in

Phys. Rev. B 110, L241102 – Published 2 December, 2024

DOI: https://doi.org/10.1103/PhysRevB.110.L241102

Abstract

We report the synthesis and properties of (H,Li)6Ru2O6, which is shown to be a Jeff=12 system made out of Ru3+ moments in a honeycomb geometry. Bulk magnetization, heat capacity, nuclear magnetic resonance (NMR), and muon spin relaxation rule out the presence of static moments or any spin glass phase down to 84 mK. All techniques suggest a crossover to a liquidlike state below about 40 K. The Li7 NMR shift data suggest a nonzero T-independent spin susceptibility at low T. In zero field, Cm/T shows T−0.9 divergence which is consistent with vacancy-induced effects on low-energy excitations of the pristine Kitaev spin liquid. With field, power-law variations in the Li7 NMR spin-lattice relaxation rate 1/T1 and magnetic heat capacity Cm show quantitatively different scaling behaviors as compared to those in H3LiIr2O6. A two-step entropy release in heat capacity is also observed putatively from Z2 flux (low-T step) and itinerant Majorana fermions (high-T step). Based on these findings, we propose that (H,Li)6Ru2O6 realizes a Kitaev spin liquid with no evidence of inherent magnetic ordering in zero field unlike α−RuCl3 where an 8-T field is required to suppress magnetic order.

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